New semiconductor materials for neutron detection
The candidate will work at CEA LITEN on the development of organic-inorganic perovskite single crystals. The solution-growth protocols will be inspired by preliminary work from several internships and PhD. The student will vary the material's structure, chemical composition, or doping in order to optimize scintillation and direct detection performances for fast neutron detection. The best compositions selected based on their structural, optical properties, and responses under X-rays will then be integrated into detectors and characterized under various neutron fluxes and energies. Their performances and durability under irradiation will be studied and benchmarked to existing materials.
Holder of a PhD in materials science or chemistry, with the ability to work with multidisciplinary teams (collaboration with the teams at CEA LETI in Grenoble, IRESNE in Cadarache, and LIST in Saclay), good autonomy, and strong organizational skills will be major assets to successfully carry out this mission.
TREATMENT OF RADIOACTIVE ORGANIC EFFLUENTS
The ECCLOR project (Project labelled 'Investment for the Future') aims to find a management route for challenging radioactive organic effluents. A strategy under investigation is to make the effluents compatible with existing outlets by decontaminating them of radioelements by column filtration. This involves developing ion-selective extractants in a form suitable for use in columns.
Studies are being carried out at CEA to improve the treatment of radioactive aqueous effluents by developing processes capable of achieving "zero discharge" while producing a minimum of waste. The challenge of the ECCLOR project will be to transpose this work to contaminated organic solvents with various radiological compositions and rheological properties. A first post-doctoral contract was dedicated to the development of materials for this application. A number of inorganic supports (silicas, geopolymers, aluminas, etc.) were considered for decontaminating these organic effluents.
The performance of the various materials developed in previous work can be optimised in terms of actinide capacity and selectivity with respect to competitor ions. In particular, the performance of existing materials needs to be studied further on more complex simulated LORs, with the necessary adaptations to the analytical method.
This project is intended for a post-doctoral fellow wishing to develop skills in extraction mechanism comprehension and analytical methods, with an interest in advancing the field of radioactive waste management. It will be will build upon the expertise of two laboratories at CEA Marcoule: the Design and Characterization of Mineral Materials Laboratory for materials elaboration and characterization, and the Supercritical and Decontamination Processes Laboratory for materials grafting and decontamination experiments.
Development of a new generation of reversible polymer adhesives
Polymeric adhesives are generally cross-linked systems used to bond two substrates throughout the lifetime of an assembly, which may be multi-material, for a wide range of applications. At their end of life, the presence of adhesives makes it difficult to separate materials and recycle them. Moreover, it is difficult to destroy the cross-linking of the adhesives without chemical or thermal treatment that is also aggressive for the bonded substrates.
In this context, the CEA is developing adhesives with enhanced recyclability, by integrating recyclability into the chemical structures right from the synthesis of the polymer networks. The first approach involves incorporating dynamic covalent bonds into polymer networks, which can be exchanged under generally thermal stimulus (e.g. vitrimers). A second approach involves synthesising polymers that can be depolymerised under a specific stimulus (self-immolating polymers) and have the ability to cross-link.
The post-doc will develop 2 networks that can be used as adhesives with enhanced recyclability. A first network will be based on a depolymerizable chemistry under stimulus already developed on linear polymer chains, to be transposed to a network. A second vitrimer network will be synthesised on the basis of previous work at the CEA. Activation of the bond exchange in this network will take place via a so-called photolatent catalyst, which can be activated by UV and will make it possible to obtain a UV- and heat-stimulated adhesive. The choice and synthesis of these catalysts and their impact on the adhesive will be the focus of the study. The catalysts obtained could also be used to trigger depolymerisation of the first depolymerisable system under stimulus.
Impact of Microstructure in Uranium Dioxide on Ballistic and Electronic Damage
During reactor irradiation, nuclear fuel pellets undergo microstructural changes. Beyond 40 GWd/tU, a High Burnup Structure (HBS) appears at the pellet periphery, where initial grains (~10 µm) fragment into sub-grains (~0.2 µm). In the pellet center, under high temperatures, weakly misoriented sub-grains also form. These changes result from energy loss by fission products, leading to defects such as dislocations and cavities. To study grain size effects on irradiation damage, nanostructured UO2 samples will be synthesized at JRC-K, using flash sintering for high-density pellets. Ion irradiation experiments will follow at JANNuS-Saclay and GSI, with structural characterizations via Raman spectroscopy, TEM, SEM-EBSD, and XRD. The postdoc project will take place at JRC-K, CEA Saclay, and CEA Cadarache under expert supervision.
Modeling of the MADISON fuel irradiation device for the future JHR reactor
The Jules Horowitz Reactor (RJH), currently under construction at CEA's Cadarache site, will irradiate materials and fuels in support of the French and international nuclear industry, as well as producing radioelements for medical use. To carry out its missions, the reactor will be equipped with numerous experimental devices. In particular, the MADISON device, currently under design, will irradiate 2 or 4 fuel samples under nominal stationary or operational transient conditions. The loop is representative of light-water reactor operating conditions, with single-phase and two-phase forced convection.
The main objective of the Post-Doc is to model the MADISON device and all associated heat exchanges precisely, in order to help determine the overall heat balance during the test and thus improve the accuracy of the linear power imposed on the samples. To this end, a coupled thermal model (describing the fuel rods and device structures) / CFD thermal-hydraulic model (describing the coolant) will be established using the NEPTUNE_CFD/SYRTHES code. The modeling will be validated based on results obtained from similar modeling carried out on the ISABELLE-1 and ADELINE single-rod devices in the OSIRIS and RJH reactors. The proposed approach fits in with the logic of developing digital twins of the RJH experimental devices.
In-situ measurement of liquid composition by digital in-line holography
This postdoctoral position is part of the ANR ATICS project (Advanced Tri-dimensional Imaging of Complex Particulate Systems), which aims to develop a set of advanced tools and methods for modeling and reconstructing holograms to enhance the practical capabilities of three-dimensional imaging through digital inline holography. This is a collaborative research project lasting four years, involving four university laboratories, the CNRS, grandes écoles, and the CEA. Within this framework, the objective of the postdoctoral work is to provide physical knowledge and data to other team members and to demonstrate the contributions of the theoretical and numerical developments made in ATICS in two research areas in which the partners are regularly involved: multiphase flows and recycling processes. To achieve this, new experimental devices for measuring the composition of liquids will be developed, leveraging the potential of inline digital holography at various scales, from microfluidics to the study of sprays in acoustic levitation. The work will be conducted in close collaboration with the teams at the IUSTI laboratory of Aix-Marseille University.
Thermochemical and thermodynamic study of chloride molten salts
In today’s climate emergency, access to clean and cheap energy is more important than ever. Several ways have been envisaged for several years now, but a number of technological issues still need to be overcome before they can be put into practice, as they represent breakthroughts. Whether for energy storage than for fourth generation nuclear reactors, molten salt environment used as coolant and/or as fuel is highly corrosive requiring a complexe choice of structural materials.
The aim of this subject proposed in the Corrosion and Materials Behavior Section is to study in depth the chemical properties of different chloride molten salts : the basic ternary salt (NaCl-MgCl2-CeCl3) but also the corrosion/fission/activation products that can be produced (MxCly with M=Cr, Fe, Te, Nd, Ni, Mo,…). The activity coefficients and solubility limits of these metallic elements will be determined using various techniques such as electrochemistry and Knudsen cell mass spectrometry. If required, this study can be completed by the phase transition temperature and heat capacity measurements using differential scanning calorimetry.
Adapting the Delayed Hydride Cracking (DHC) experience to irradiated materials
The objective of this study is to nuclearize the Delayed Hydride Cracking (DHC) experiment developed as part of Pierrick FRANCOIS PhD research (2020-2023). This experiment enables the reproduction of the DHC phenomenon in Zircaloy cladding under laboratory conditions to determine the material's fracture toughness in case of DHC: KI_DHC.
The term "nuclearize" refers to the adaptation of the experiment to test irradiated materials within dedicated shielded enclosures (called hot cells), where materials are handled using remote manipulators. The experimental protocols described in Pierrick FRANCOIS' thesis must therefore be modified, and ideally simplified, to allow for their implementation in hot cells. This will require close collaboration with the personnel responsible for the tests and the use of numerical simulation tools developed during the same PhD research.
The development of this hot cell procedure will be used by the postdoctoral researcher to assess the risk of HC during dry storage of spent fuel assemblies by quantifying the fracture toughness of irradiated claddings.
Optimizing phytotechnologies for the remediation of contaminated nuclear sites
CEA is recruiting a postdoctoral researcher for a research project aimed at optimizing phytotechnologies for the remediation of contaminated nuclear sites. This research is part of the risk management and remediation of contaminated soils, in particular those resulting from the decommissioning of nuclear facilities. The aim of the project is to develop an advanced mechanistic model of soil-plant transfers, in order to gain a better understanding of contaminant mobility in lightly contaminated soils, and to optimize the use of suitable plants to stabilize these contaminants.
Development of new Potassium-ion cells with high performances and low environmental impact
Lithium ion batteries are considered as the reference system in terms of energy density and cycle life and will play a key role in the energetic transition, especially concerning electric vehicles. However, such a technology involves the use of a large amount of critical elements and active materials are synthesised using energy intensive processes.
In this way, our team is developing a new Potassium-ion batteries technology with high performances but with a low environmental impact.
For this innovative and ambitious project, CEA-LITEN (one of the most important research institute in Europe) is looking for a talented post-doctoral researcher in material chemistry. The post-doctoral position is opened for a young researcher with a high scientific level, interested by valorising her/his results through different patents and/or scientific publications.