Development of an innovative anode based on non-critical and sustainable materials for anion-exchange membrane electrolysis
Anion-exchange membrane water electrolysis (AEMWE) is a recent and promising technology for producing green hydrogen, but it still faces major challenges in terms of performance and durability. Currently, the anodes used in AEMWE electrolyzers consist of two layers: a porous transport layer (PTL), which enables the circulation of electrolyte and gases, and an active layer made of catalysts and binders, where the electrochemical reactions take place. This configuration limits reactant diffusion and reduces the available active surface area, which negatively impacts overall performance.
This PhD project aims to develop an innovative anode based on non-critical materials by combining the advantages of both layers while minimizing their drawbacks. The idea is to functionalize the PTL directly by adding catalyst nanoparticles and/or by applying a surface activation treatment, in order to confer electrochemical activity. These modifications are expected to improve electron and reactant transport while increasing the active surface area for the oxygen evolution reaction (OER).
The work carried out in this thesis will involve functionalizing a pre-selected PTL and characterizing the resulting anodes through structural and electrochemical analyses. The expected outcomes include the development of an optimized anode with enhanced performance and limited degradation, as well as a deeper understanding of the limiting phenomena in AEMWE anodes. This project is part of a broader effort to develop sustainable technologies essential for the energy transition.
Contribution in the study of Power Partial Converters in Energy sources Hybridization
One of the key areas for reducing the carbon footprint is transport, particularly the development of electric mobility, which is currently growing rapidly. In this context, the hybrid electric transport market is growing. Hybridization applications have seen their power increase and with it that of power electronics converters allowing to adapt the voltage levels of energy sources and the energy exchanges between them. This increase in power is accompanied by higher losses to be evacuated, resulting in a significant impact firstly on the size of the converters, and therefore of the overall system, and then on the energy efficiency of the entire chain. Efforts have already been made at CEA-LITEN to develop high-efficiency DC-DC converters (in particular by using interleaved DC-DC converters). The objective of the thesis will be to go further by studying the so-called partial power converters (PPC). The different architectures/topologies will be studied for hybrid applications associating a fuel cell and a battery on the one hand, and applications associating 2 batteries (one power type battery and the other, energy type battery) on the other hand. The work aims to determine the best architecture/topologies for each of the typical applications allowing a significant reduction in the size of the converters and the improvement of the efficiency of the whole system
Control coordination of power converters on the distribution grid to enhance overal system stability
With the increasing number of generation and consumption units connected through power electronic converters, the electrical grid is evolving toward a more dynamic and decentralized structure. This transformation strengthens both the need and the potential for these converters to actively contribute to system flexibility and stability—particularly in compensating for renewable energy fluctuations and maintaining the balance between supply and demand.
Optimized coordination of their control functions offers significant potential to improve grid resilience, by intelligently leveraging their capabilities in voltage regulation, frequency support, and reactive power control. However, to integrate these contributions effectively at scale, it is essential to develop holistic modeling approaches that capture multi-scale interactions—both in time and space.
The modeling work in this thesis aims to represent the relationship between the active/reactive power flexibility of power electronic converters and the stability margin they provide to the grid, as well as to model the aggregation of their actions for system-wide contribution. Building on this foundation, coordinated control architectures and algorithms between the distribution and transmission networks will be investigated, developed, and validated.
Evaluation of the impact of dry extrusion process on cathode microstructure and performances for polymer-based solid-state batteries
Solid-state batteries (SSB) are expected to outperform standard lithium-ion technology in terms of energy density and safety, with application in electric vehicles or stationary energy storage. Manufacturing of these new battery technologies can rely on existing infrastructure (solvent-based electrode slurry mixing and coating) or need new processing methods. In this context, twin-screw extrusion process exhibits several advantages when applied to SSB, particularly with polymer-based electrolytes.
To speed up the implementation of polymer-based SSB, a better understanding of extrusion process applied to positive electrode manufacturing is needed. The objective of this thesis is to develop new electrode formulations using hot-melt extrusion and understand the impact of process parameters on final performances. It should finally give a clear picture about the advantages and limitations of extrusion compared to standard wet casting.
This PhD project will be part of a collaboration between CEA and Stellantis on the development of new solid-state batteries. The study will focus on the development of extrusion-processed composite electrodes to be used in polymer-based SSB. First, materials will be selected and characterized for a preliminary screening of formulations using lab-scale extrusion. Then, a systematic evaluation of the impact of input materials and operational conditions during extrusion process will be undertaken to highlight the relationships between process, electrode microstructures and performances. Finally, the best performing electrode formulations will be integrated in a fully-extruded prototype and characterized by electrical tests as well as post-mortem analysis.
The PhD candidate will benefit from CEA-LITEN's multidisciplinary environment (Grenoble campus) and Stellantis industrial know-how. Battery Prototyping Platform will be used for extrusion trials and cell assembly, whereas access to advanced characterization equipment (SEM, XPS, rheometers, electrochemical methods, etc.) will guarantee deep understanding of underlying mechanisms.
Heat Transfer Enhancement by Convective Boiling in Microchannels applied to the Cooling of Computing Units in Data Centers
The proposed PhD thesis aims to improve the understanding and modeling of convective boiling phenomena in microchannels for new low-environmental-impact refrigerants. The candidate will adopt a combined experimental and multi-scale modeling approach, including the design of a test bench simulating the behavior of a micro-evaporator, the implementation of CFD simulations (ANSYS Fluent, CATHARE) to describe two-phase flow regimes, and the evaluation of various eco-friendly alternative fluids. The expected outcomes include, for each of these new fluids, the characterization of confined boiling mechanisms, the development of a predictive heat transfer model, and the proposal of innovative cooling solutions.
The growing demand for high-performance computing, driven by artificial intelligence and cloud technologies, leads to a significant increase in power dissipation in electronic chips. Current single-phase cooling technologies are reaching their limits when dealing with heat fluxes exceeding 100 W/cm². Two-phase cooling, based on fluid boiling to remove heat, can achieve much higher heat transfer performance than single-phase systems while reducing overall energy consumption. The results of this research will contribute to the development of more efficient and sustainable cooling solutions for future data centers, helping to reduce the digital sector’s energy footprint and strengthen European technological sovereignty in advanced cooling technologies.
Advancing Lithium-Sulfur Batteries through the study of the Quasi-Solid Sulfur Conversion
Lithium–sulfur batteries are widely seen as one of the most promising candidates for the next generation of energy storage, offering the potential for significantly higher energy density than today’s batteries while using abundant and inexpensive sulfur. However, several scientific and technological challenges still prevent their large-scale industrial deployment.
One key issue is the formation of soluble lithium polysulfides during battery operation, which can migrate inside the cell and lead to rapid capacity loss. Recent research suggests that a different reaction pathway, known as a “quasi-solid mechanism”, could limit this dissolution and significantly improve battery stability.
This PhD project aims to design and study lithium–sulfur pouch cells operating through this quasi-solid mechanism. The work will combine materials development, electrochemical testing, and advanced characterization techniques to better understand the processes governing battery performance and durability.
The project will focus on two complementary research directions:
1. Design of advanced sulfur cathodes
The first part of the work will involve developing optimized sulfur-based cathodes. This includes exploring different conductive host materials and tuning their structure and surface properties to better confine sulfur and reduce unwanted reactions.
2. Development of improved electrolytes
The second part of the project will focus on electrolyte formulations that reduce the solubility of polysulfides while maintaining good battery performance. Current solutions often rely on dense, fluorinated solvents that increase cost and environmental impact. This project will explore alternative solvent systems and investigate how salt composition and concentration influence cell behaviour.
To gain deeper insight into the quasi-solid reaction mechanism, the project may also involve operando or in-situ characterization techniques, such as Raman spectroscopy, X-ray diffraction, and high-resolution X-ray tomography.
Study of the Metastability of Silicon Heterojunction Solar Cells and Stabilization Strategies
Silicon-based photovoltaic cells, particularly silicon heterojunction (SHJ) cells using hydrogenated amorphous silicon (a-Si:H), achieve efficiencies exceeding 25%. However, these architectures exhibit intrinsic metastability, such as Staebler-Wronski degradation, which can lead to efficiency losses during storage between fabrication and module assembly. In the context of globalized supply chains, these instabilities represent an economic and technical risk that is not yet well quantified. This thesis aims to address the following questions: what is the quantitative impact of instability on the efficiency of high-efficiency cells during prolonged storage? What are the physical mechanisms responsible for this degradation? What technological strategies can reduce or eliminate this instability? What are the industrial implications for module logistics? To achieve this, a rigorous experimental protocol will be implemented to monitor the electrical performance of cells over several months under varying storage conditions (atmosphere, temperature, humidity). Test structures and advanced characterizations (FTIR, Raman, Silvaco TCAD) will be used to understand the underlying physical phenomena. Process optimization, introduction of new materials, and improved packaging will be explored to stabilize the cells. Practical recommendations for the industry, regarding maximum storage durations and optimal storage conditions, will also be established. The goal is to develop technological and logistical solutions to minimize efficiency losses in SHJ cells, optimize supply chains, and reduce associated economic risks.
Development of Machine Learning algorithm to optimize the control of absorption machines
The Thermal and Solar Technologies Laboratory (L2TS) and the Energy Systems for Territories Laboratory (LSET), located at the CEA LITEN site in Le Bourget-de-Lac, are offering a cross-disciplinary PhD thesis combining thermodynamics and optimization using Artificial Intelligence.
Specifically, this doctoral research project involves developing a machine learning algorithm to optimize the control of absorption machines. These machines are thermodynamic cycles able to produce heat or cold from an intermediate heat input; thus, offering potential valorization of industrial waste heat or renewable energies, such as solar thermal. Heat exchange is made possible by the absorption and desorption reactions of a gaseous refrigerant in a fluid. Specifically, the NH3-H2O mixture will be used. The dynamic operation of these cycles is extremely complex because the operational variables, physical parameters, and hydrodynamic aspects are highly intertwined. Thus, the use of a neural network is particularly relevant for establishing an adaptive control strategy for these machines.
The thesis will have a theoretical aspect, involving the study and selection of the most suitable algorithm to address the problem, and an experimental aspect of validation on a prototype absorption machine. The project will also involve the design of a controller for implementation.
The thesis will take place in a CEA laboratory in Bourget du Lac.
Development and characterization of a low-silver metallization for photovoltaic cells with high-efficiency passivated contacts
In order to decarbonize energy production and meet climate plan objectives, the production of photovoltaic (PV) modules must increase significantly. To sustain these production levels, the silver content in latest-generation cells must be drastically reduced. Some alternatives incorporate less expensive metals (nickel, aluminum, copper) into screen-printing pastes. These approaches require evaluation in terms of contact formation, electron transport, and reliability. In a TOPCon cell architecture, the electrode must be brought into direct contact with the active layers of the cell via thermal annealing. This step enhances device performance (through a hydrogenation phenomenon) while simultaneously generating potential degradation related to the introduction of metallic species. This is especially critical when using new metals (Ni, Cu, etc.) with higher diffusivities than silver. The objectives of this thesis are manifold: to evaluate the performance of these low-silver alternative pastes once integrated into TOPCon cells; to characterize the impact of the introduction of these metallic species on the lifetime of photogenerated carriers in silicon; and to assess the long-term stability of these metallizations while verifying the absence of cell degradation phenomena under prolonged illumination. If necessary, an alternative metallization technique more suitable for these pastes will be developed. During the PhD, the successful candidate will be required to fabricate, metallize via screen printing, and characterize devices within a cleanroom environment.
Self-healing of radiation-induced defects in silicon solar cells for space
Over the last decades, the development of alternative space photovoltaic (PV) solutions to the III-V premium standard has shifted the focus to silicon solar cells. Indeed, leveraging on existing maturity of terrestrial PV silicon devices and processes offers significant potential for innovation and cost reduction. Many satellites nowadays evolve in Low Earth Orbit, a proton and electron rich environment. Such irradiations induce electrically active defects in the material which affect the PV performances. Interestingly, some of the irradiation-induced defects can be healed upon external factors such as temperature and/or photons flux.
The main goals of this PhD thesis will be to i) understand the bulk & interface electron/proton irradiation-induced degradation mechanisms driving the evolution of the optoelectronic properties of silicon passivated contacts solar cells ii) develop a comprehensive understanding of the self-healing effects in irradiated modern silicon solar cells through experimental studies and modeling iii) identify design / fabrication process routes to control & boost the self-healing capability.
To reach these goals, this PhD work will go through defined steps: bibliography review, solar cells fabrication, material/device ageing under proton & electron irradiations, advanced characterizations and modeling. This PhD work will be conducted at CEA/Liten, on the INES campus (Le Bourget du Lac, FR) with frequent interactions with CNES (Toulouse, FR) facilities.