2D materials electrical characterization for microelectronics
Future microelectronic components will be ever smaller and ever more energy-efficient. To meet this challenge, 2D materials are excellent candidates, thanks to their remarkable dimensions and electronic properties (high mobility of charge carriers, high light emission/absorption). What's more, they feature van der Waals (vdW) surfaces, i.e. no dangling bonds, enabling them to retain their properties even at very small dimensions (down to the monolayer). New 2D materials and vdW stacks with novel physical properties are being discovered every day. However, integrating them and measuring their performance in circuits remains an ongoing challenge, as their properties must be preserved during integration.
The aim of this post-doc is to develop components for qualifying 2D materials for microelectronic (RF transistor) and spintronic (magnetic memory) applications in horizontal configuration on silicon. A vertical measurement method has already been developed by CEA LETI. Building on these developments, the candidate will develop this measurement system and characterize various materials produced in MBE by CEA-IRIG. The work will involve transferring these layers onto chips, optimizing the electrical contacts and developing the in-plane electrical measurement chain.
Disruptive RF substrates based on polycrystalline materials
A high resistivity substrate is essential for the design of state-of-the-art high-frequency circuits. The high-resistivity (HR) SOI substrate with a trap-rich layer below the buried oxide (BOX) is the option with the highest performance at present for CMOS technologies. However, these substrates have two major limitations: (1) their relatively high price and (2) the degradation of their RF performance at operating temperatures above 100 °C.
As part of this postdoctoral study, we propose to study, in collaboration with the Catholic University of Louvain (UCL), the RF performance over a wide temperature range of a polycrystalline substrate over its entire thickness (several hundred µm). These polycrystalline substrates indeed have a high density of electronic traps distributed throughout the entire volume, which in principle allows for stable RF performance even at high operating temperatures.
The person hired will participate in the following research: (1) screening of promising substrates from TCAD simulations (e.g. poly-Si, poly-SiC, …), (2) integration of polycrystalline substrates in an SOI process flow at Leti, (3) measurement of RF performances in frequency and temperature at UCL. A particular attention will be placed on understanding the physical phenomena involved through the comparison of experimental and simulation data.
Preparation and optimization of HiPIMS PVD coatings for corrosion protection of nickel alloys in molten chloride environments
The aim of this post-doctoral project is to demonstrate the effectiveness and performance of various materials - metals, oxides and ceramics - that can be used as coatings on nickel alloys intended for the construction of a molten-salt reactor. Coatings deposited by HiPIMS PVD will be subjected to microscopic and structural characterization to optimize deposition parameters. Corrosion experiments in a molten-salt environment will then be used to verify the performance of these coatings, and to identify degradation mechanisms to remedy them. The most promising compositions can be optimized by the addition of minor elements, a development involving multi-target PVD devices.
In situ analysis of dislocations with Molecular Dynamics
Thanks to new supercomputer architectures, classical molecular dynamics (MD) simulations will soon reach the scale of a trillion atoms. These unprecedentedly large simulation systems will thus be capable of representing metal plasticity at the micron scale. Such simulations generate an enormous amount of data, and the challenge now lies in processing them to extract statistically relevant features for the mesoscale plasticity models (continuous-scale models).
The evolution of a material is complex as it depends on extended crystal defect lines (dislocations), whose dynamics are governed by numerous mechanisms. To feed higher-scale models, the key quantities to extract are the velocities and lengths of dislocations, as well as their evolution over time. These data can be extracted using specific post-processing techniques based on local environment characterization ('distortion score' [Goryaeva_2020], 'local deformation' [Lafourcade_2018], ‘DXA’ [Stukowski_2012]). However, these methods remain computationally expensive and do not allow for in situ processing.
We have recently developed a robust method for real-time identification of crystalline structures [Lafourcade_2023], which will soon be extended to dislocation classification. The objective of this postdoctoral project is to develop a complete analysis pipeline leading to the in situ identification of dislocations in atomic-scale simulations and their extraction in a nodal representation.
Preparation and characterization of an oxide/oxide composite
Fiber-reinforced ceramic matrix composites (CMCs) are a class of materials that combine good specific mechanical properties (properties relative to their density) with resistance to high temperatures (> 1000 °C), even in oxidizing atmospheres. They are typically composed of a carbon or ceramic fiber reinforcement and a ceramic matrix (carbide or oxide.
The proposed study focuses on the development of a low-matrix oxide/oxide CMC with suitable dielectric, thermal, and mechanical properties.
This study will be conducted in collaboration with several laboratories at CEA Le Ripault.
Development of new Potassium-ion cells with high performances and low environmental impact
Lithium ion batteries are considered as the reference system in terms of energy density and cycle life and will play a key role in the energetic transition, especially concerning electric vehicles. However, such a technology involves the use of a large amount of critical elements and active materials are synthesised using energy intensive processes.
In this way, our team is developing a new Potassium-ion batteries technology with high performances but with a low environmental impact.
For this innovative and ambitious project, CEA-LITEN (one of the most important research institute in Europe) is looking for a talented post-doctoral researcher in material chemistry. The post-doctoral position is opened for a young researcher with a high scientific level, interested by valorising her/his results through different patents and/or scientific publications.
Influence of laser bandwidth and wavelength on laser plasma instabilities
As part of the Taranis project initiated by Thales and supported by BPI France and in collaboration with numerous scientific partners such as CEA/DAM, CELIA and LULI, work on target design and definition of the laser intended to energy production in direct drive will take place. A prerequisite for this work is to understand the laser-plasma interaction mechanisms that will occur when the laser is coupled with the target. These deleterious mechanisms for the success of fusion experiments can be regulated by the use of so-called “broadband” lasers. In addition, the choice of the laser wavelength used for the target design and the laser architecture must be defined. The objective of the postdoctoral position is to study the growth and evolution of these instabilities (Brillouin, Raman) in the presence of “broadband” lasers both from an experimental and simulation point of view, and thus to be able to define the laser conditions making it possible to reduce these parametric instabilities.
Separation microsystem coupled to mass spectrometry for on-line purification and characterisation of nuclear samples
The miniaturisation of analytical steps commonly carried out in laboratories offers many advantages and particularly in the nuclear sector, where the reduction of material consumption and waste production is of major interest. In this context, one of our laboratory’s focus area is the miniaturisation of analytical tools, particularly chromatographic separation techniques. The aim of this project is to reduce the scale of the purification steps of nuclear samples by solid phase extraction chromatography, prior to the analytical processes. Obtaining these miniaturised extraction devices is based on the in situ synthesis and anchoring of monoliths, in the channels of cyclic olefin copolymer (COC) microsystems. Since this material is chemically inert, COC functionalisation strategies are currently under development to covalently graft reactive sites on its surface, before locally anchoring actinide-specific monoliths in the micro-channels. The aim is to design and fabricate chromatographic extraction microsystems in COC, and to implement them for chemical purification and mass spectrometry measurements, both off-line and on-line.
Experimental and technological developments of a process for the mineralization of organic liquid waste by plasma
The ELIPSE process developed at the CEA allows the destruction of organic liquids by injection into a high-power plasma.
If the feasibility of destroying different organic components at flow rates of a few liters per hour has now been demonstrated, tests must now be further developed for reference organic liquids appropriately chosen according to existing deposits.
These studies, based on the characterization data of the chosen LORs, will aim to provide detailed process results obtained with the most representative operating conditions, to allow a complete and quantitative evaluation of the process. This will make it possible to establish operating, robustness and endurance data for the process.
This work will include the study of the behavior of radioelements in the process, which will be essential for the nuclearization study: this will involve studying the physico-chemical behavior of actinides during their processing via the use of inactive simulants.