Kinetic study of biocide effect in nanocellulose_based food film
This project will study the kinetic of biocide effect of a nanocellulose-based film food. The main aim is to graft Ag and/or ZnO NPs on and inside halloysite particles that have a characteristic shape of twisted sheets and therefore could acting as NPs tanks. The localization of NPs outside halloysite could induce a fast biocide effect with limited duration whereas the internal grafting could produce longer biocide effect. This project gathers all steps from the film food synthesis, its nanocharacterization to the evaluation of its toxicological effect on bacteria. The final goal is to find one or many halloysite functionalizations allowing to extend the biocide effect in film food and to transpose it to other types of materials.
Silicon nanowire elaboration for microelectronic applications
In order to realize high capacity integrated capacitor, one approach consists in developing electrode with high specific surface. In this work, we propose to perform capacitor integrating silicon nanowires. The first part of this study will be devoted to the understanding and to the optimization of Si nanowires CVD growth process. In parallel, properties of nanowires obtained by electrochemical silicon etching will be assessed and will be compared to CVD nanowires characteristics. According to the electrical performances, different strategies (metallization Silicuration…) will be envisaged in order to enhance their electrical conductivity.
Characterisation of vanadium alloys
Vanadium alloys, investigated in the scope of application in fusion reactors, are potential candidates for fuel cladding of future sodium cooled or gas cooled fasts reactors. Then, in 2009, CEA launched a program aiming to assess this solution according to future reactor requirements.
Preliminary investigation of V-4Cr-4Ti plates was done at DMN/SRMA/LA2M (i) on a reference Japanese grade and (ii) on a specific grade fabricated for CEA study. Works haw focuses on recrystallisation structure after cold working (grain size and morphology, effect of annealing temperature), and on fine microstructure (occurrence of Ti(O,C,N) precipitation). In 2011, fabrication of vanadium tube by hot extrusion is planned to be relevant of the final cladding geometry. The proposed post-doc investigation aims to monitor the fabrication and to specify the impact of fabrication process on microstructure, recrystallisation dynamic and mechanical properties.