Development of a new generation of reversible polymer adhesives
Polymeric adhesives are generally cross-linked systems used to bond two substrates throughout the lifetime of an assembly, which may be multi-material, for a wide range of applications. At their end of life, the presence of adhesives makes it difficult to separate materials and recycle them. Moreover, it is difficult to destroy the cross-linking of the adhesives without chemical or thermal treatment that is also aggressive for the bonded substrates.
In this context, the CEA is developing adhesives with enhanced recyclability, by integrating recyclability into the chemical structures right from the synthesis of the polymer networks. The first approach involves incorporating dynamic covalent bonds into polymer networks, which can be exchanged under generally thermal stimulus (e.g. vitrimers). A second approach involves synthesising polymers that can be depolymerised under a specific stimulus (self-immolating polymers) and have the ability to cross-link.
The post-doc will develop 2 networks that can be used as adhesives with enhanced recyclability. A first network will be based on a depolymerizable chemistry under stimulus already developed on linear polymer chains, to be transposed to a network. A second vitrimer network will be synthesised on the basis of previous work at the CEA. Activation of the bond exchange in this network will take place via a so-called photolatent catalyst, which can be activated by UV and will make it possible to obtain a UV- and heat-stimulated adhesive. The choice and synthesis of these catalysts and their impact on the adhesive will be the focus of the study. The catalysts obtained could also be used to trigger depolymerisation of the first depolymerisable system under stimulus.
Design and Implementation of a Neural Network for Thermo-Mechanical Simulation in Additive Manufacturing
The WAAM (Wire Arc Additive Manufacturing) process is a metal additive manufacturing method that allows for the production of large parts with a high deposition rate. However, this process results in highly stressed and deformed parts, making it complex to predict their geometric and mechanical characteristics. Thermomechanical modeling is crucial for predicting these deformations, but it requires significant computational resources and long calculation times. The NEUROWAAM project aims to develop a precise and fast thermomechanical numerical model using neural networks to predict the physical phenomena of the WAAM process. An internship in 2025 will provide a database through thermomechanical simulations using the CAST3M software. The post-doc's objective is to develop a neural network architecture capable of learning the relationship between the manufacturing configuration and the thermomechanical characteristics of the parts. Manufacturing tests on the CEA's PRISMA platform will be conducted to validate the model and prepare a feedback loop. The CEA List's Interactive Simulation Laboratory will contribute its expertise in accelerating simulations through neural networks and active learning to reduce training time.
Contribution to the metrological traceability of emerging alpha-emitting radiopharmaceuticals in the framework of the european AlphaMet project (Metrology for Emerging Targeted Alpha Therapies)
The Laboratoire national Henri Becquerel (LNE-LNHB) at CEA/Saclay is the laboratory responsible for the french references in the field of ionizing radiation. The LNHB is involved in the european EPM AlphaMet (Metrology for Emerging Targeted Alpha Therapies) submitted under the Metrology support for Health call (2022) to provide metrological support for clinical and preclinical studies; it began in September 2023 for a total duration of three years. The project comprises four Work Packages (WP) targeting different issues, with WP1 in particular dedicated to activity metrology and nuclear data measurements for imaging and dosimetry. This project aims at to improve the metrological traceability of emerging alpha-emitting radiopharmaceuticals such as 211At, 212Pb/212Bi, 225Ac.
The candidate will participate in the various tasks defined as part of the European AlphaMet project in which the LNHB is involved. Radiation-matter simulations will be carried out to study the response of the laboratory's ionisation chambers in various situations concerning: (i) the evolution of the response during the in-growth of the ?-emitting progeny of 225Ac, (ii) the quantification of the influence of the 210At impurity in the case of the measurement of 211At, and (iii) the search for a long-lived radionuclide surrogate of 212Pb for the quality control of dose calibrators. The candidate will also be involved in setting up a new device aimed at improving the linearity of the measurement of half-life with an ionization chamber. During the post-doctoral stay at LNHB, the candidate will interact with the various partners in the AlphaMet project (activity metrology laboratories, hospitals, clinical study centres).
The initial duration of the post-doctorate is 12 months (renewable) at the Laboratoire National Henri Becquerel (CEA/Saclay). It is hoped to start in the first half of 2024.
Hydrogen permeation in metals
In the context of developing the hydrogen sector, understanding the interactions between hydrogen and materials is a key challenge.
When hydrogen comes into contact with metallic materials, it can dissolve into the matrix and diffuse through it—a phenomenon known as permeation.
Hydrogen permeation measurements in metals have been developed at the CEA-Grenoble for over 20 years.
The objective of this post-doctoral project is to investigate these permeation phenomena when hydrogen is introduced at high pressure and when pollutants are present in the hydrogen.
The project will begin with the design and implementation of a new permeation test bench, which must enable high-pressure testing and precise control of impurity levels in the hydrogen.
Subsequently, the study will focus on the effect of pressure and impurities on hydrogen permeation in ferrito-pearlitic steels, using the previously developed test bench.
Development of innovative metal contacts for 2D-material field-effect-transistors
Further scaling of Si-based devices below 10nm gate length is becoming challenging due to the control of thin channel thickness. For gate length smaller than 10nm, sub-5nm thick Si channel is required. However, the process-induced Si consumption and the reduction of carrier mobility in ultrathin Si layer can limit the channel thickness scaling. Today, the main contenders that allow the extension of the roadmap to ultra-scaled devices are 2D materials, particularly the semiconducting transition metal dichalcogenides (TMD). Due to their unique atomically layered structure, they offer improved immunity to short-channel-effects in comparison to usual Si-based field-effect-transistors (FETs). This makes them very attractive for the application of more-Moore electronics.
However, the scalability of MOSFET device and the introduction of new material make source and drain contact a major issue. If many efforts have been made, in the past years, to reduce Fermi level pinning and Schottky barrier height, for many, these approaches are not industrially scalable. The main objective of this work is then to propose an in-depth understanding of electrical contact characteristics (based on different material) to identify the lowest contact resistance. The processes involved, offering an optimal contact resistance, must be compatible with wafer-scale processing for an integration in our 200/300mm advanced CMOS platform. The post-doc will in-depth study mechanisms enabling the formation of small contact resistances (between MoS2 and metal). It will have to identify the most promising contact material and to develop the associated deposition processes (ALD/PVD). Finally, electrical characterization of contact will be performed to qualify both material and interfaces enabling optimal operation of future 2D FETs
Superconducting BEOL integration for upcoming quantum devices
Controlling and manipulating quantum information using advanced nanoelectronic technologies represents a major challenge currently undertaken by CEA-LETI and its partners. A key objective of this project is to achieve the integration of quantum devices within Fully Depleted Silicon-On-Insulator (FD-SOI) technology on a 300 mm platform. The success of this integration critically depends on the development of superconducting interconnects, which are essential for ensuring the thermomagnetic isolation of quantum devices in addition to ensuring the electrical continuity of the device.
The proposed integration scheme builds on a CEA-LETI patent that enabled the fabrication of TaN/TiN-based superconducting interconnections, exhibiting a critical temperature (Tc) on the order of one kelvin. The goal of this research project is to explore the integration of superconducting materials with higher critical temperatures (around ten Kelvins) in order to enhance thermomagnetic isolation and improve overall device performance. This postdoctoral project aims to investigate the potential of newly developed high-temperature superconducting materials — such as ZrN, HfN, and NbTiN — produced by ICPMS-CNT and CEA-LETI, as well as their integration into the existing process flow. Using an innovative direct etch approach, the postdoc will study the impact of the process step on the superconducting properties. The influence of line dimensions on the superconducting properties such as critical temperature and current density of the materials will be also investigated. Based on the results obtained, process and integration adjustments will be proposed to optimize performances.
Development and application of TERS/TEPL technique for advanced characterization of materials
TERS/TEPL (Tip-Enhanced Raman Spectroscopy and Tip-Enhanced Photoluminescence) are powerful analytical techniques developed for nanoscale material characterization. The recent acquisition of a unique and versatile TERS/TEPL equipment at PFNC (Nano-characterization Platform) of CEA LETI opens up new horizons for materials characterization. This tool combines Raman spectroscopy, photoluminescence, and scanning probe microscopy. It features multi-wavelength capabilities (from UV to NIR), allowing a wide range of applications and providing unparalleled insights into the composition, structure, and mechanical/electrical properties of materials at nanoscale resolution. The current project aims to develop and accelerate the implementation of the TERS/TEPL techniques at PFNC to fully exploit its potential in diverse ongoing projects at CEA-Grenoble (LETI/LITEN/IRIG) and with its partners.
Batteries recycling :Development and understanding of a new deactivation concept of lithium ion domestic batteries
Domestic lithium ion batteries gather all batteries used in electronic devices, mobile phone, and tooling applications. By 2030, the domestic lithium-ion battery market will increase up to 30%. With the new European recycling regulation and the emergency to find greener and safer recycling process, it is today necessary to develop new deactivation process of domestic lithium ion batteries.
The process has to address several lithium ion chemistries, be continuous, safe, controllable and low cost.
To develop this new concept, the first step will be to define the most appropriate chemical systems. Then these chemical systems will be tested in a dedicated experimental laboratory setup using chemistry and electrochemistry, allowing the simulation of real conditions of domestic batteries deactivation.
The third step will be to characterize, understand and validate the electrochemical and physico chemical mechanisms. The last step will be to participate to the validation of the deactivation concept on a real object (a lap top battery) in representative conditions (on the abuse tests plateform of CEA).
Unsupervised Few-Shot Detection of Signal Anomalies
Our laboratory, located at Digiteo in CEA Saclay, is looking for a postdoc candidate working on the subject of anomaly detection in manufacturing processes, for a duration of 18 months starting from Feburary 2022. This postdoc is part of HIASCI (Hybridation des IA et de la Simulation pour le Contrôle Industriel), a CEA LIST project in an internal collaboration which aims at building a platform of AI methods and tools for manufacturing applications, ranging from quality control to process monitoring. Our laboratory contributes to HIASCI by developping efficient methods of anomaly detection in acoustic or vibrational signals, operating with small amounts of training data. In this context, the detection of signal anomalies (DSA) consists of extracting from data the information about the physical process of manufacturing, which is in general too complex to be fully understood. Moreover, real data of abnormal states are relatively scarce and often expensive to collect. For these reasons we privilege a data-driven approach under the framework of Few-Shot Learning (FSL).
Application of formal methods for interferences management
Within a multidisciplinary technological research team of experts in SW/HW co-design tools by applying formal methods, you will be involved in a national research project aiming at developing an environment to identify, analyze and reduce the interferences generated by the concurrent execution of applications on a heterogeneous commercial-off-the-shelf (COTS) multi-core hardware platform.