Integrated material–process–device co-optimization for the design of high-performance RF transistors on advanced nanometer technologies
This PhD research focuses on the integrated co-optimization of materials, fabrication processes and device architectures to enable high-performance RF transistors on advanced nanometer-scale technologies. The work aims to understand and improve key RF figures of merit—such as transit frequency, maximum oscillation frequency, noise behaviour and linearity—by establishing clear links between material choices, process innovations and transistor design.
The project combines experimental development, structural and electrical characterization, and advanced TCAD simulations to analyse the strengths and limitations of different integration schemes, including FD-SOI and emerging 3D architectures such as GAA and CFET. Particular attention will be given to the engineering of optimized spacers, gate stacks, junction placement and epitaxial source/drain materials in order to minimize parasitic effects and enhance RF efficiency.
By comparing planar and 3D device platforms within a unified modelling and characterization framework, the thesis aims to provide technology guidelines for future generations of energy-efficient RF transistors targeting applications in 5G/6G communications, automotive radar and low-power IoT systems.
III-V semiconductor nanoplatelets
Colloidal semiconductor nanoplatelets (NPLs) are a class of two-dimensional nanostructures that have electronic and optical properties distinct from those of spherical quantum dots (QDs). They exhibit strong quantum confinement in a single dimension, their thickness, which can be controlled on the monolayer level using solution chemistry. As a result, NPLs emit light with an extremely narrow spectral width and at the same time, they have a very high absorption coefficients. These properties make them ideal candidates for various applications (e.g., light-emitting diodes for low-power-consumption displays, photocatalysis, single-photon emitters).
At present, only the synthesis of metal chalcogenide NPLs has been mastered. These materials either contain toxic elements (CdSe, HgTe, etc.) or have a large bandgap (ZnS, ZnSe). For these reasons, the development of synthesis methods for III-V semiconductor NPLs, such as InP, InAs and InSb is currently a major challenge. In this thesis, we will develop new synthetic approaches for the growth of InP NPLs, exploring different avenues and using in situ characterizations as well as machine learning assisted design of experiments. Numerical simulations will be used to determine the reactivity of precursors and to model the mechanisms inducing anisotropic growth.
Modeling and characterization of CFET transistors for enhanced electrical performance
Complementary Field Effect Transistors (CFETs) represent a new generation of vertically stacked CMOS devices, offering a promising path to continue transistor miniaturization and to meet the requirements of high-performance computing.
The objective of this PhD work is to study and optimize the strain engineering of the transistor channel in order to enhance carrier mobility and improve the overall electrical performance of CFET devices. The work will combine numerical modeling of technological processes using finite element methods with experimental characterization of crystalline deformation through transmission electron microscopy coupled with precession electron diffraction (TEM-PED).
The modeling activity will focus on predicting strain distributions and their impact on electrical properties, while accurately accounting for the complexity of the technological stacks and critical fabrication steps such as epitaxy. In parallel, the experimental work will aim to quantify strain fields using TEM-PED and to compare these results with simulation outputs.
This research will contribute to the development of dedicated modeling tools and advanced characterization methodologies adapted to CFET architectures, with the goal of improving spatial resolution, measurement reproducibility, and the overall understanding of strain mechanisms in next-generation transistors.
Investigation and Modeling of Ferroelectric and Antiferroelectric Domain Dynamics in HfO2-Based Capacitors
The proposed PhD work lies within the exploration of new supercapacitor and hybrid energy storage technologies, aiming to combine miniaturization, high power density, and CMOS process compatibility. The hosting laboratory (LTEI/DCOS/LCRE) has recognized expertise in thin-film integration and dielectric material engineering, offering unique opportunities to investigate ferroelectric (FE) and antiferroelectric (AFE) behaviors in doped hafnium oxide (HfO2).
The thesis will focus on the experimental investigation and physical modeling of thin-film HfO2-based capacitors, intentionally doped to exhibit ferroelectric or antiferroelectric properties depending on the composition and deposition conditions (for instance, through ZrO2 or SiO2 doping). Such materials are particularly attractive for realizing devices that combine non-volatile memory and energy storage functions on a single CMOS-compatible platform, enabling ultra-low-power autonomous systems such as edge computing architectures, environmental sensors, and smart connected objects.
The research will involve the fabrication and characterization of metal–insulator–metal (MIM) capacitors based on doped HfO2 integrated on silicon substrates. Systematic electrical measurements—including current–voltage (I–V) and polarization–electric field (P–E) characterizations—will be carried out under various frequencies, amplitudes, and cycling conditions to investigate the relaxation mechanisms of FE and AFE domains. Analysis of minor hysteresis loops will provide access to the distribution of activation energies and enable the modeling of domain relaxation dynamics. A physical model will be developed or refined to describe FE/AFE transitions under cyclic electrical excitation, incorporating effects such as charge trapping, mechanical stress, and domain nucleation kinetics.
The overall objective is to optimize the recoverable energy density and the energy conversion efficiency of these capacitors, while establishing design guidelines for compact, efficient, and silicon-integrable energy storage devices. The insights gained from this work will contribute to a deeper understanding of the dynamic mechanisms governing FE/AFE behavior in doped HfO2, with potential impact on ferroelectric memories, energy-harvesting devices, and low-power neuromorphic architectures.
Fabrication of Metasurfaces by Self-Assembly of Block Copolymers
Block copolymers (BCP) are an industrial technology in full expansion, offering promising perspectives for material nanostructuring. These polymers, composed of chemically distinct block chains, self-assemble to form ordered structures at the nanometric scale. However, their current use is limited to specific nanostructuring per product (1 product = 1 nanostructuring), thus restricting their application potential.
This PhD proposes to develop an innovative method to create multiple patterns in a single BCP self-assembly step using a mixture of two products. The student will also focus on controlling the localization of these patterns using chemoepitaxy, a technique combining chemical and morphological guidance to precisely control the position of patterns at the micrometric and nanometric scales.
The work will proceed in several steps: understanding the mechanisms of mixed block copolymers, developing functionalized substrates for chemoepitaxy using advanced lithography techniques, and conducting BCP self-assembly experiments on these substrates. The resulting structures will be analyzed using the metrology equipment available at CEA-Leti.
The targeted applications include the creation of nanostructures capable of interacting with light, reducing diffraction, and controlling polarization. The expected results include demonstrating the ability to generate multiple types of patterns in a single self-assembly step, with precise control over their position and dimensions.
Multiscale modeling of rare earth ion emission from ionic liquids under intense electric fields
The main objective of this thesis is to model the mechanisms of rare earth ion emission from ionic liquids subjected to an intense electric field, in order to identify the conditions favorable to the emission of weakly complexed ions.
The aim is to establish rational criteria for the design of new ILIS sources suitable for the localized implantation of rare earths in photonic devices.
The thesis work will be based on large-scale molecular dynamics simulations, reproducing the emission region of a Taylor cone under an electric field.
The simulations will be compared with emission experiments conducted in parallel by the SIMUL group in collaboration with Orsay Physics TESCAN, using a prototype ILIS source doped with rare earths. Comparisons of measurements (mass spectrometry, energy distribution) will enable the models to be adjusted and the proposed mechanisms to be validated.
Bayesian Neural Inference Using Ferroelectric Memory Transistors
An increasing number of safety-critical systems now rely on artificial intelligence functions that must operate under strict energy constraints and in environments characterized by data scarcity and high uncertainty. However, conventional deterministic AI approaches provide only point estimates and lack principled uncertainty quantification, which can lead to unreliable or unsafe decisions in real-world deployment.
This PhD is positioned within the emerging field of Bayesian electronics, which aims to implement probabilistic inference directly in hardware by leveraging the intrinsic stochasticity of nanoscale devices to represent and manipulate probability distributions. While memristive devices have previously been explored for Bayesian inference, their limited endurance and high programming energy remain critical bottlenecks for on-chip learning.
The objective of this thesis is to investigate ferroelectric field-effect memory transistors (FeMFETs) as building blocks for hardware Bayesian neural networks. The work will involve characterizing and modeling the exploitable ferroelectric randomness for sampling and probabilistic weight updates, designing Bayesian neuron and synapse architectures based on FeMFETs, and evaluating their robustness, energy efficiency, and system-level performance for safety-critical inference under uncertainty.
Development and Characterization of Terahertz Source Matrices Co-integrated in Silicon and III-V Photonics Technology
The terahertz (THz) range (0.1–10 THz) is increasingly exploited for imaging and spectroscopy (e.g. security scanning, medical diagnostics, non-destructive testing) because many materials are transparent to THz radiation and have unique spectral signatures. However, existing sources struggle to offer both high power and wide tunability: electronic sources (diodes, QCLs) deliver milliwatts but over narrow bands, while photonic emitters (photomixers in III–V semiconductors) are tunable across broad bands but emit only microwatts. This thesis aims to overcome these limitations by developing an integrated matrix of THz sources. The approach is based on photomixing two 1.55 µm lasers in III–V photodiodes to generate a phase-coherent THz current coupled to THz antennas.
Initially, the PhD student will experimentally investigate an existing 16-element THz antenna array (STYX project) CEA-CTReg/DNAQ: setting up the test bench, measuring phase coherence, optical coupling, radiation lobes, and constructive interference. These experiments will provide a scientific foundation for the subsequent design of an integrated photonic array on silicon. The student will simulate the photonic architecture (couplers, waveguides, phase modulators, Si/III–V transitions) synchronizing multiple InGaAs photodiodes. Prototyping will include the fabrication of silicon photonic circuits (CEA-LETI) and THz photodiodes/antennas in InP (III-V Lab or, to be confirmed, Heinrich-Hertz-Institut of the Fraunhofer—HHI), followed by their hybrid integration (bonding, alignment).
This thesis will also rely on close collaboration with the IMS laboratory (Bordeaux), which is nationally and internationally recognized for its expertise in silicon photonics and THz systems. IMS will provide complementary expertise in optical modeling, electromagnetic simulation, and experimental characterization, reinforcing the multidisciplinary strength of the project.
Finally, the ultimate goal of this thesis is to develop a proof-of-concept demonstrator with a few phase-locked THz emitters (e.g. 4–16) will be produced and characterized, showing enhanced beam directivity and output power thanks to constructive interference. This demonstration will pave the way for large-scale THz source arrays with significantly improved range and penetration for advanced THz imaging systems.