Development of ultra-high-resolution magnetic microcalorimeters for isotopic analysis of actinides by X-ray and gamma-ray spectrometry

The PhD project focuses on the development of ultra-high-resolution magnetic microcalorimeters (MMCs) to improve the isotopic analysis of actinides (uranium, plutonium) by X- and gamma-ray spectrometry around 100 keV. This type of analysis, which is essential for the nuclear fuel cycle and non-proliferation efforts, traditionally relies on HPGe detectors, whose limited energy resolution constrains measurement accuracy. To overcome these limitations, the project aims to employ cryogenic MMC detectors operating at temperatures below 100 mK, capable of achieving energy resolutions ten times better than that of HPGe detectors. The MMCs will be microfabricated at CNRS/C2N using superconducting and paramagnetic microstructures, and subsequently tested at LNHB. Once calibrated, they will be used to precisely measure the photon spectra of actinides in order to determine the fundamental atomic and nuclear parameters of the isotopes under study with high accuracy. The resulting data will enhance the nuclear and atomic databases used in deconvolution codes, thereby enabling more reliable and precise isotopic analysis of actinides.

How defects nucleation affects the the fracture on the SmartCut process

The SmartCut™ technology is widely used in microelectronics for the fabrication of innovative substrates, such as SOI (Silicon-on-Insulator).
The physical phenomena underlying SmartCut™ technology remain one of principal interest of our research. Optimizing the fracture stage is a major focus in our laboratory and in our collaboration with Soitec. Salomon's PhD thesis (expected completion December 2026), the development of post-fracture surface analysis protocols highlighted the link between the evolution of cristalline defects that cause fracture (platelets) and post-fracture surface roughness. We were thus able to characterize the early stages of platelet growth and determine their main characteristics (size and density). This had previously only been achieved through complex characterizations based on TEM observations.

Now that we have highlighted the impact of platelets on post-fracture surface roughness, the next step is to investigate and identify ways to control their nucleation using new processes. This will also involve optimizing the post-fracture state of SOI substrates.

CdTe for medical radiography; control of electrical properties

The use of direct-conversion detectors in medical radiography opens up new possibilities. Due to its properties, the semiconductor material CdTe has emerged as the material of choice for manufacturing these new components. The proposed thesis topic aims to develop the knowledge and processes necessary to produce CdTe crystals with properties tailored to specific application requirements. The work will draw on the laboratory’s advanced expertise in mastering CdTe single-crystal growth processes. The key challenges of the project will be as follows:
- Performing annealing under controlled atmospheres (ex-situ, on small samples) to study their impact on the electrical properties of CdTe,
- Conducting advanced characterizations to better understand the doping mechanisms in CdTe,
- Fabricating “simple” devices and testing them under X-ray flux to quantify the performance of the laboratory’s materials.
The proposed thesis topic is central to the development of a CdTe technology for medical radiography applications. Multidisciplinary work (material and process development, material characterization, fabrication and X-ray testing of simplified devices) is proposed to address this topic.

New methodologies for analyzing the impact of crystal defects on the electrical performance of SiC power devices

In our past studies on SiC power devices, the analysis of electrical performances on diodes [1] (idem for future MOSFETs) must take into account the impact of material's defects at the epitaxy and substrate level.
Initially, the thesis work will consist of setting up tools dedicated to our needs in the SiC team. The specifications for these tools have already been established as part of the internship currently underway within the LAPS laboratory. These AI tools will be able to be trained on already existing datasets (SiC diode batches: with electrical data, defect mappings) and complete the previous manually carried out analyses.
In a second phase, the use of the developed tools will be applied to new manufactured and characterized batches. The range of data will then be completed by considering new component architectures (diodes and power MOSFETs), new material characterizations (defects characterization from other tools being installed at Leti, or even with external collaborators: see Line Pilot WBG, see Soitec), new entries (images of defectivity, obtained during the components fabrication in the clean rooms).
Note that the approach applies i) in the case of power to other materials (GaN, diamond, Ga2O3...), ii) also potentially to any component on semiconductor (memory, transistor, photonic, quantum...).

Growth of Inorganic Halide Perovskite 2D/3D Heterostructures via Pulsed Laser Deposition (PLD) for Optoelectronics and Photovoltaics

Halide perovskites (HPs) have demonstrated exceptional potential in photovoltaics (PV), achieving record efficiencies (35% in silicon-based tandem cells). However, their limited stability (degradation under humidity, heat, or light) and scalability challenges (efficiency loss at large scale) hinder industrial adoption. Concurrently, in microLED applications, HPs are emerging as a promising alternative to quantum dots (QDs) for color conversion layers, thanks to their high spectral purity and superior absorption. Yet, their efficiency and stability still require optimization to compete with existing solutions.

This project proposes an innovative approach: fabricating inorganic 2D perovskites and 2D/3D heterostructures via pulsed laser deposition (PLD), a scalable and unexplored method for perovskites. 2D perovskites, due to their quantum confinement, exhibit high exciton binding energy, making them ideal for LEDs and lasers, while 2D/3D heterostructures enhance stability and reduce non-radiative recombination.

The thesis objectives are:
1. Synthesis of inorganic 2D perovskites (lead-free and lead-based) via PLD and advanced material characterization (crystallinity, luminescence, absorption, bandgap, stability).
2. Fabrication of 2D/3D heterostructures to achieve defect passivation in 3D layers, with advanced characterization (photoluminescence yield, carrier lifetime, interface passivation).
3. Application in PV and microLEDs: evaluating potential for tandem solar cells and color conversion layers.
The results aim to demonstrate that PLD can overcome current limitations (stability, large-scale production) while maintaining competitive optoelectronic performance. This work aligns with global efforts where perovskites could drive significant advancements in PV and microdisplays

An electrochemical flow microreactor for a greener synthesis of gold nanoparticles

Gold nanoparticles (AuNPs) possess unique electronic, photonic, and chemical properties of invaluable interest in a variety of medical and technological applications. They are typically produced by controlled chemical precipitation from a salt solution to achieve the precise size control critical for most applications. Continuous flow microreactors, which efficiently mix the salt solution and the reducing agent, are known to offer improved size control. However, even in these reactors, the smallest AuNPs can only be formed using powerful reducing agents that are harmful to human health or the environment. We propose to minimize their impact and to develop a more resource-efficient process by inserting an electrochemical cell into the reactor to form the reducing agent in-situ in the adjusted amount necessary to produce the desired AuNPs.
Your goal will be to test and adapt continuous-flow electrochemical cells for the synthesis of AuNPs, exploring various electrochemical reactions and cell designs. You will also explore the use of several capping agents of biological interest. A careful examination of AuNPs characteristics (size, interfacial and optical properties, etc.) will guide you in this research.

Topologically Isolated Mode Acoustic Resonators

Timing is a key function in electronic circuits. Beyond on-chip signals synchronization, it also allows the synchronization of wireless data transmissions. Accurate time references require stable frequency sources, which also benefit to sensor applications. The gold standard for time or frequency generation is still quartz resonators, which are however bulky and difficult to miniaturize. Research is therefore still ongoing to provide high quality factor (> 10,000) resonators, ideally capable of operating at frequencies of several GHz. A key to reach such high quality factors is to confine strongly the mechanical vibration of micro-size structures in order to make them insensitive to external perturbations. Recently, the field of topological acoustics has demonstrated the capability to confine elastic waves in very small volumes concentrated at the interface between periodic structure, and to provide extremely high quality factor resonances.
This PhD position focuses on exploiting topologically protected modes in piezoelectric microstructures to provide next generations of high quality factor resonators, which may be used in oscillators or even filter circuits. Leveraging the know-how of CEA Leti in the design and fabrication of such components, the PhD will be part of an international collaboration with well established academic laboratories (Politecnico di Milano, Imperial College FEMTO-ST Institute) and industrial partners.
The candidate will model and design structures supporting topologically protected modes, combinining finite element simulations with simplified numerical approaches which reduce computation times. He will follow the fabrication of demonstrators in collaboration with the process integration teams in the CEA Leti clean rooms, and carry on measurements of the proposed resonators.

High-Endurance Chalcogenide Memories for Next-Generation AI

Discover a unique phd opportunity where you will dive into the heart of innovation in memory technologies. You will develop strong expertise in areas such as electrical characterization and the understanding of degradation phenomena in chalcogenide-based memories.

By joining our multidisciplinary teams, you will play a key role in studying and improving the endurance of Phase-Change Memory (PCM) and Threshold Change Memory (TCM) devices—two promising technologies for high-performance artificial intelligence applications. You will take part in innovative projects combining scientific rigor and applied research on nanoscale devices, working closely with another CEA PhD student who conducts advanced physico-chemical analyses (TEM) to investigate degradation mechanisms.

You will have the opportunity to contribute actively to tasks such as:

Electrical characterization of PCM and TCM devices to analyze cycling-induced degradation
Development and evaluation of innovative programming protocols to extend endurance limits
Proposing solutions to improve the reliability and performance of next-generation memories
Regular collaboration and discussion with the CEA PhD student to interpret TEM results and draw conclusions about degradation mechanisms

Study of Failure Modes and Mechanisms in RF Switches Based on Phase-Change Materials

Switches based on phase change materials (PCM) demonstrate excellent RF performance (FOM <10fs) and can be co-integrated into the BEOL of CMOS processes. However, their reliability is still very little studied today. Failure modes such as heater breakage, segregation, or the appearance of cavities in the material are shown during endurance tests, but the mechanisms of these failures are not discussed. The objective of this thesis will therefore be to study the failure modes and mechanisms for different operating conditions (endurance, hold, power). The analysis will be carried out through electrical and physical characterizations and accelerated aging methods will be implemented.

Dies to wafer direct bonding: from physical mechanisms to the development of thin stackable dies

Direct dies-to-wafer bonding has become, in recent years, a major development axis in microelectronics and at the heart of many LETI projects, both in silicon photonics and for 3D applications involving hybrid bonding.

Due to their small size, die bonding allows the study of direct bonding edge effects and the implementation of new direct bonding processes that can shed original light on the mechanisms of direct bonding, which are already well studied at LETI. From a more technological perspective, the development of thin stackable chips will also be a very interesting technological key for many applications. This approach is a clever alternative to classical damascene processes to address the challenges related to the planarization of surfaces with low density of high topographies.

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