Fabrication of Metasurfaces by Self-Assembly of Block Copolymers
Block copolymers (BCP) are an industrial technology in full expansion, offering promising perspectives for material nanostructuring. These polymers, composed of chemically distinct block chains, self-assemble to form ordered structures at the nanometric scale. However, their current use is limited to specific nanostructuring per product (1 product = 1 nanostructuring), thus restricting their application potential.
This PhD proposes to develop an innovative method to create multiple patterns in a single BCP self-assembly step using a mixture of two products. The student will also focus on controlling the localization of these patterns using chemoepitaxy, a technique combining chemical and morphological guidance to precisely control the position of patterns at the micrometric and nanometric scales.
The work will proceed in several steps: understanding the mechanisms of mixed block copolymers, developing functionalized substrates for chemoepitaxy using advanced lithography techniques, and conducting BCP self-assembly experiments on these substrates. The resulting structures will be analyzed using the metrology equipment available at CEA-Leti.
The targeted applications include the creation of nanostructures capable of interacting with light, reducing diffraction, and controlling polarization. The expected results include demonstrating the ability to generate multiple types of patterns in a single self-assembly step, with precise control over their position and dimensions.
Multiscale modeling of rare earth ion emission from ionic liquids under intense electric fields
The main objective of this thesis is to model the mechanisms of rare earth ion emission from ionic liquids subjected to an intense electric field, in order to identify the conditions favorable to the emission of weakly complexed ions.
The aim is to establish rational criteria for the design of new ILIS sources suitable for the localized implantation of rare earths in photonic devices.
The thesis work will be based on large-scale molecular dynamics simulations, reproducing the emission region of a Taylor cone under an electric field.
The simulations will be compared with emission experiments conducted in parallel by the SIMUL group in collaboration with Orsay Physics TESCAN, using a prototype ILIS source doped with rare earths. Comparisons of measurements (mass spectrometry, energy distribution) will enable the models to be adjusted and the proposed mechanisms to be validated.
Bayesian Neural Inference Using Ferroelectric Memory Transistors
An increasing number of safety-critical systems now rely on artificial intelligence functions that must operate under strict energy constraints and in environments characterized by data scarcity and high uncertainty. However, conventional deterministic AI approaches provide only point estimates and lack principled uncertainty quantification, which can lead to unreliable or unsafe decisions in real-world deployment.
This PhD is positioned within the emerging field of Bayesian electronics, which aims to implement probabilistic inference directly in hardware by leveraging the intrinsic stochasticity of nanoscale devices to represent and manipulate probability distributions. While memristive devices have previously been explored for Bayesian inference, their limited endurance and high programming energy remain critical bottlenecks for on-chip learning.
The objective of this thesis is to investigate ferroelectric field-effect memory transistors (FeMFETs) as building blocks for hardware Bayesian neural networks. The work will involve characterizing and modeling the exploitable ferroelectric randomness for sampling and probabilistic weight updates, designing Bayesian neuron and synapse architectures based on FeMFETs, and evaluating their robustness, energy efficiency, and system-level performance for safety-critical inference under uncertainty.
Development and Characterization of Terahertz Source Matrices Co-integrated in Silicon and III-V Photonics Technology
The terahertz (THz) range (0.1–10 THz) is increasingly exploited for imaging and spectroscopy (e.g. security scanning, medical diagnostics, non-destructive testing) because many materials are transparent to THz radiation and have unique spectral signatures. However, existing sources struggle to offer both high power and wide tunability: electronic sources (diodes, QCLs) deliver milliwatts but over narrow bands, while photonic emitters (photomixers in III–V semiconductors) are tunable across broad bands but emit only microwatts. This thesis aims to overcome these limitations by developing an integrated matrix of THz sources. The approach is based on photomixing two 1.55 µm lasers in III–V photodiodes to generate a phase-coherent THz current coupled to THz antennas.
Initially, the PhD student will experimentally investigate an existing 16-element THz antenna array (STYX project) CEA-CTReg/DNAQ: setting up the test bench, measuring phase coherence, optical coupling, radiation lobes, and constructive interference. These experiments will provide a scientific foundation for the subsequent design of an integrated photonic array on silicon. The student will simulate the photonic architecture (couplers, waveguides, phase modulators, Si/III–V transitions) synchronizing multiple InGaAs photodiodes. Prototyping will include the fabrication of silicon photonic circuits (CEA-LETI) and THz photodiodes/antennas in InP (III-V Lab or, to be confirmed, Heinrich-Hertz-Institut of the Fraunhofer—HHI), followed by their hybrid integration (bonding, alignment).
This thesis will also rely on close collaboration with the IMS laboratory (Bordeaux), which is nationally and internationally recognized for its expertise in silicon photonics and THz systems. IMS will provide complementary expertise in optical modeling, electromagnetic simulation, and experimental characterization, reinforcing the multidisciplinary strength of the project.
Finally, the ultimate goal of this thesis is to develop a proof-of-concept demonstrator with a few phase-locked THz emitters (e.g. 4–16) will be produced and characterized, showing enhanced beam directivity and output power thanks to constructive interference. This demonstration will pave the way for large-scale THz source arrays with significantly improved range and penetration for advanced THz imaging systems.