Lightweight and high-strength metamaterials with innovative architectures manufactured by additive manufacturing for constrained environments

Environmental constraints, rising raw material costs, and the need to reduce carbon footprints drive the development of more porous materials that combine lightness with mechanical strength. Such materials meet the requirements of strategic sectors including aerospace, space, transportation, energy, and high-performance physics instruments.

Mechanical metamaterials, composed of micro-lattice structures produced by 3D printing, offer a unique potential to address these challenges. By tailoring the topology of their internal networks, it becomes possible to achieve stiffness-to-density ratios higher than those of conventional materials and to adapt their architecture to target specific mechanical or functional properties.

This thesis is part of this wave of innovation. It aims to develop ultralight metallic metamaterials whose architecture is optimized to maximize mechanical performance while maintaining isotropy, ensuring predictable behavior using conventional engineering tools, including finite element analysis, numerical simulation, and multiscale approaches. The research builds on the recognized expertise of the CEA, particularly at IRAMIS and IRFU/DIS, in designing isotropic random metastructures and shaping them through metal additive manufacturing.

By combining numerical mechanics, advanced design, multi-process additive manufacturing, and in situ characterization, this thesis seeks to push the current limits of design and fabrication of complex metallic structures.

Acoustic imaging on irradiated fuel elements : from implementation to interpretation in terms of Metal/Ceramic interface

To improve the flexibility of civil nuclear reactors, many research programs are conducted by CEA in support of the French nuclear plants operator EDF and fuel fabricant FRAMATOME, specifically concerning the behaviour of fuel elements under irradiation.
The fuel elements consist of a metallic cladding and ceramic pellets. In case of power variations, the presence of a gap between the cladding and the pellets, and the bonding between them in case of contact, are fundamental for the mechanical strength of the fuel element.
To complete the current characterizations after irradiation of the pellet-cladding interface, the feasibility of a non-destructive method based on acoustic imaging has been studied and validated.
As a continuation of this first study, the objective of the thesis is to complete instrumentation of an operating measurement bench with the acoustic measurement chain. This bench is located in a cell which is dedicated to examinations of irradiated fuel elements.
The thesis work includes preparation and implementation of a qualification protocol of the acoustic chain, with images acquisitions on irradiated fuel elements. Acoustic signals processing will be developed to correct the effects of the external corrosion layer. Final expected results are images representing axial and azimuthal localization of the contact or gap between the cladding and the pellets, and the fraction of the bonding zones.
The PhD student will be based within IRESNE, an Institute of the CEA localized in Cadarache (in the south of France) which is specialized in the Research for Nuclear Systems for Low Carbon Energy Production. The work will take place in a nuclear installation which is equipped with various tools for multiscale characterization of the irradiated fuel from nuclear or experimental reactors.
This multidisciplinary work will be carried out in collaboration with a team from IES (Institute for Electronic and Systems - CNRS - Montpellier). This team is specialized in acoustic developments from probes to complete imaging systems.
Thanks to the resources and expertise of the two entities CEA and IES, the student will acquire solid skills in the fields of modeling, instrumentation and metrology. Results will be valorised in international publications and communications.

Chemo-mechanical modeling of the coupling between carbonation, rebar corrosion and cracking in cementitious materials

Rebar corrosion is one of the main causes of premature degradation of concrete infrastructures, including in the nuclear sector, where concrete is extensively used in containment structures and waste storage facilities. Carbonation, caused by the penetration of CO2 into the concrete, lowers the pH of the pore solution, promoting rebar corrosion. This corrosion leads to the formation of expansive products that can cause cracking in the material. The proposed thesis work, developed as part of a European collaborative project between CEA Saclay, École des Mines de Paris - PSL, and IRSN, aims to develop a numerical model to simulate these phenomena. The model combines a reactive transport code (Hytec) and a finite element code (Cast3M) to study the local effects of carbonation-induced corrosion on concrete cracking. This project will benefit from parallel experimental work to gather data for parameter identification and model validation. The first part of the research will focus on modeling the carbonation of cementitious materials under unsaturated conditions, while the second part will address the corrosion of rebar caused by the pH drop induced by carbonation. The model will describe the growth of corrosion products and their expansion, inducing stress within the concrete and potential microcracking.
This research project is aimed at a PhD student wishing to develop their skills in materials science, with a strong focus on multi-physical and multi-scale modeling and numerical simulations. The thesis will be carried out principally at CEA Saclay and at École des Mines de Paris – PSL (Fontainebleau).

Assessment of new models for the investigation of hypothetical accidents in GEN4 fast reactors.

Multi-component two-phase flows in conjunction with fluid-structure interaction (FSI) problems can occur in a very large variety of engineering applications; amongst them, the hypothetical severe accidents postulated in Generation IV sodium and lead fast-breeder reactors (respectively SFR and LFR).
In SFRs, the worst postulated severe accident is the so-called hypothetical core disruptive accident (HCDA), in which the partial melt of the core of the reactor interacts with the surrounding sodium and creates a high-pressure gas bubble, the expansion of which generates shock waves and is responsible of the motion of liquid sodium, thus eventually damaging internal and surrounding structures.
The LFR presents the advantage that, unlike sodium, lead does not chemically react with air and water and, therefore, is explosion-proof and fire-safe. On the one hand, this allows a steam generator inside the primary coolant. On the other hand, the so-called steam generator tube ruptures (SGTR) should be investigated to guarantee that, in the case of this hypothetical accident the structure integrity is preserved. In the first stage of a SGTR, it is supposed that the steam-generator high-pressure high-temperature water penetrates inside the primary containment, thus generating a BLEVE (boiling liquid expanding vapor explosion) with the same behavior and consequences as the high-pressure gas bubble of a HCDA.
In both HCDA and STGR, there are situations in which the multi-component two-phase flows is in low Mach number regime which, when studied with classical compressible solver, presents problems of loss of accuracy and efficiency. The purpose of this PhD is
* to design a multiphase solver, accurate and robust, to investigate HCDA STGR scenarios.
* to design a low Mach number approach for bubble expansion problem, based on the artificial compressibility method presented in the recent paper "Beccantini et al., Computer and fluids 2024".
The aspect FSI will be also taken into account.

Understanding the signals emitted by moving liquids

Elasticity is one of the oldest physical properties of condensed matter. It is expressed by a constant of proportionality G between the applied stress (s) and the deformation (?): s = G.? (Hooke's law). The absence of resistance to shear deformation (G' = 0) indicates liquid-like behavior (Maxwell model). Long considered specific to solids, shear elasticity has recently been identified in liquids at the submillimeter scale [1].
The identification of liquid shear elasticity (non-zero G') is a promise of discoveries of new liquid properties. For example, do we know that a confined liquid changes temperature under flow? Yet no classical model (Poiseuille, Navier-Stokes, Maxwell) predicts the effect because without long-range correlation between molecules (i.e. without elasticity), the flow is dissipative, therefore athermal. For a change in temperature to be flow induced (without a heat source), the liquid must have elasticity and this elasticity must be stressed [1,2].
The PhD thesis will explore how the mechanical energy of the flow is converted in a thermal response [2]. We will exploit the capacity of conversion to develop a new generation of microfluidic devices (patent FR2206312).
We will also explore the impact of the wetting on the liquid flow, and reciprocally, we will examine how the liquid flow modifies the solid dynamics (THz) of the substrate [3]. Powerful methods only available in Very Large Research Facilities such as the ILL will be used to probe the non-equilibrium state of solid phonons. Finally, we will strengthen our existing collaborations with theoreticians.

The PhD topic is related to wetting, macroscopic thermal effects, phonon dynamics and liquid transport.

1. A. Zaccone, K. Trachenko, “Explaining the low-frequency shear elasticity of confined liquids" PNAS, 117 (2020) 19653–19655. Doi:10.1073/pnas.2010787117
2. E. Kume, P. Baroni, L. Noirez, “Strain-induced violation of temperature uniformity in mesoscale liquids” Sci. Rep. 10 13340 (2020). Doi : 10.1038/s41598-020-69404-1.
3. M. Warburton, J. Ablett, P. Baroni, JP Rueff, L. Paolasini, L. Noirez, “Identification by Inelastic X-Ray scattering of bulk alteration of solid dynamics due to Liquid Wetting”, J. of Molecular Liquids 391 (2023) 123342202

Design of asynchronous algorithms for solving the neutron transport equation on massively parallel and heterogeneous architectures

This PhD thesis work aims at designing an efficient solver for the solution to the neutron transport equation in Cartesian and hexagonal geometries for heterogeneous and massively parallel architectures. This goal can be achieved with the design of optimal algorithms with parallel and asynchronous programming models.
The industrial framework for this work is in solving the Boltzmann equation associated to the transportof neutrons in a nuclear reactor core. At present, more and more modern simulation codes employ an upwind discontinuous Galerkin finite element scheme for Cartesian and hexagonal meshes of the required domain.This work extends previous research which have been carried out recently to explore the solving step ondistributed computing architectures which we have not yet tackled in our context. It will require the cou-pling of algorithmic and numerical strategies along with programming model which allows an asynchronousparallelism framework to solve the transport equation efficiently.
This research work will be part of the numerical simulation of nuclear reactors. These multiphysics computations are very expensive as they require time-dependent neutron transport calculations for the severe power excursions for instance. The strategy proposed in this research endeavour will decrease thecomputational burden and time for a given accuracy, and coupled to a massively parallel and asynchronousmodel, may define an efficient neutronic solver for multiphysics applications.
Through this PhD research work, the candidate will be able to apply for research vacancies in highperformance numerical simulation for complex physical problems.

Simulation of flow in centrifugal extractors: the impact of viscous solvents on operation

Within the framework of nuclear spent fuel reprocessing, the CEA co-developed with ROUSSELET-ROBATEL liquid/liquid extraction (ELL) devices aimed at bringing two immiscible liquids into contact, one of which contains the valuable metals to be recovered and the other an extractant molecule. The multi-stage Centrifugal Extractor is one of the devices used to perform ELL at the La Hague plant. The future use of solvents potentially more viscous than current industrial standards may pose performance issues that need to be studied in advance in the laboratory to provide the necessary recommendations to restore the expected performance levels for the plant. The nuclear environment in which these devices operate makes in situ studies nearly impossible, thus depriving R&D of valuable information that is nevertheless essential for a deep understanding of the physicochemical mechanisms at the heart of the issues involved. To address this, the proposed study will rely on a numerical approach that will have been previously validated by comparison with either historical experimental data or data acquired from more recent ad hoc pilot systems. Thus, following a phase of literature review and capitalization of recent measurements, it is proposed to first create test cases that will be used to validate the numerical models. Based on this validation and in light of the knowledge acquired from previous theses concerning the effect of viscosity on flows, it is proposed to numerically explore the impact of an increase in solvent viscosity on centrifugal extractors. This will pave the way for a better understanding of the operation of the devices as well as operational or geometric improvements. The student will work at CEA Marcoule, in a research environment at the crossroads between a team of experimentalists and a team of numerical simulators. This experience will enable the student to acquire important skills in modeling liquid-liquid flows as well as solid knowledge on the development of liquid-liquid contactors.

Design and test of a PLL in FD-SOI 28nm technology

The goal of this PhD thesis is to design a Phase Locked Loop for generic use at 5 GHz. This PLL will also include a study regarding each building bloc sensitivity to radiation and thermal sensitivity regarding space environment. This is the main point of this PhD thesis because integrating a PLL in harsh environment requires an accurate knowledge of the circuit's parameters. The candidate will begin its work by analysing existing works on the FD-SOI technology (structure characteristics and impact on radiation hardening) to serve as a base for its work and design a Phase Locked Loop architecture. He will also study how to characterise each PLL building bloc variations in harsh environment (radiation and temperature).

Euclid Weak Lensing Cluster Cosmology inference

Galaxy clusters, which form at the intersection of matter filaments, are excellent tracers of the large-scale matter distribution in the Universe and are a valuable source of information for cosmology.
The sensitivity of the Euclid space mission (launch in 2023) allow blind detection of galaxy clusters through gravitational lensing (i.e. directly linked to the projected total mass). Combined with its wide survey area (14,000 deg²), Euclid should allow the construction of a galaxy cluster catalogue that is unique in both its size and selection properties.
In contrast to existing cluster catalogues, which are typically based on baryonic content (e.g., X-ray emission from intra-cluster gas, the Sunyaev-Zel’dovich effect in the millimeter regime, or optical emission from galaxies), a catalogue derived from gravitational lensing is directly sensitive to the total mass of the clusters. This makes it truly representative of the underlying cluster population, a significant advantage for both galaxy cluster studies and cosmology.
In this context, we have developed a multi-scale detection method specifically designed to identify galaxy clusters based only on their gravitational lensing signal, which has been pre-selected to produce the Euclid cluster catalogue.
The goal of this PhD project is to build and characterize the galaxy cluster catalogue identified via weak lensing in the data collected during the first year of Euclid observations (DR1), based on this detection method. The candidate will derive cosmological constraints from the modelling of the cluster abundance, using the classical Bayesian framework, and will also investigate the potential of Simulation-Based Inference (SBI) methods for cosmological inference.

Optically Pumped Magnetometers based on helium-3

The laboratory, reknown for its expertise in high-resolution and high-precision magnetic measurements, has been developing and providing for several decades successive generations of optically pumped helium-4 magnetometers. These instruments serve as reference sensors aboard the ESA Swarm mission satellites launched in late 2013, and will also equip the forthcoming NanoMagSat mission, scheduled to launch from the end of 2027 onward.

In an effort to diversify its activities and to address emerging applications involving autonomous or “deploy-and-forget” sensors, where power consumption constraints are particularly demanding, the laboratory now aims to develop a new magnetometer technology based on helium-3 atoms as the sensitive medium. The lifetime of the helium-3 atomic state used for magnetic field measurement is significantly longer than that of the equivalent helium-4 state. This property enables a substantial reduction in optical pumping requirements, thereby offering the prospect of improved energy efficiency and power consumption.

The objective of this research is to advance the Technology Readiness Level (TRL) of this helium-3-based magnetometer architecture, with the ultimate goal of realizing an instrument that combines outstanding metrological performance with exceptional energy frugality, suited to these highly specific and constrained applications.

Accordingly, the purpose of this PhD work will be to design, implement, and experimentally evaluate a helium-3 magnetometer architecture capable of fulfilling these performance and efficiency objectives.

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