Increasing the electrothermal robustness of new SiC devices
Silicon Carbide (SiC) is a semiconductor with superior intrinsic properties than Silicon for high temperature and high power electronics applications. SiC devices are expected to be extensively used in the electrification transition and novel energy management applications. To fully exploit the SiC superior properties, the future semiconductor devices will be used under extreme biasing and temperature conditions. These devices must operate safely at higher current densities, higher dV/dt and higher junction temperatures than Si devices does.
The objective of this thesis is to study the SiC devices fabricated at LETI under these extreme operating conditions, and to optimize their design to fully use the theoretical potential of SiC. The thesis work will include several phases that will be strongly coupled:
- Advanced electro-thermal characterisation (50%), by proposing new approaches to testing components in a box or on a suitable support, using artificial intelligence (AI) tools for data extraction and processing. The work will include adapting standard measurement methodologies to the specific switching characteristics of SiC.
- An assessment (15%) of the design and technological parameters responsible for the operating limits of the components.
- A physico-chemical characterisation component (15%) to analyse failures under these extreme conditions.
- The inclusion of predictive models (20%) for the sensitivity of architectures to extreme conditions and faults, based on modelling.
Design and optimization of color routers for image sensors
Color routers represent a promising technology that could revolutionize the field of image sensors. Composed of nanometricstructures called metasurfaces, these devices allow the modification of light propagation to improve the quantum efficiency of pixels. Thanks to recent technical advances, it is now possible to design and manufacture these structures, paving the way for more efficient image sensors.
The thesis topic focuses on the design and optimization of color routers for image sensors. Several research avenues will be explored, such as the implementation of new metasurfacegeometries (`freeform`) or innovative configurations to reduce pixel pitch (0.5µm or 0.6µm). Various optimization methods can be used, such as the adjointmethod, machine learning, or the use of auto-differentiable solvers. The designs must be resilient to the angle of light incidence and expected variations during manufacturing. After this simulation phase, the proposed structures will be manufactured, and the student will have the mission to characterize the chips and analyze the obtained results (quantum efficiency, modulation transfer function...).
This thesis will be co-supervised by STMicroelectronics and CEA LETI in Grenoble. The student will be integrated into the teams of engineer-researchers working on this project. He/she will be led to collaborate with various specialists in various fields such as lithography and optical characterization.
The student's main activities:
- Optical simulation using numerical methods (FDTD, RCWA)
- Development of optimization methodologies for metasurfacedesign (adjointmethod, topological optimization...)
- Electro-optical characterization and analysis of experimental data
CTC electrolyte pour LiS system
Lithium-Sulfur (Li-S) Batteries are among the most promising energy storage technologies for the fifth generation of batteries, often referred to as post-Li-ion. With a theoretical energy density five times higher than that of conventional Li-ion batteries and an abundant availability of sulfur, the Li-S system offers a unique potential to meet the growing demand for sustainable energy storage. However, current technology is limited by major challenges related to the dissolution of polysulfides in the electrolyte, leading to active sulfur loss, poor cycle life, and insufficient electrochemical performance. These limitations currently hinder the market deployment of this technology.
This thesis aims to explore an alternative approach based on an all-solid electrochemical sulfur conversion mechanism. To achieve this, a next-generation organic solid electrolyte developed in the laboratory will be implemented. This electrolyte features a unique lithium-ion conduction mechanism within a crystalline lattice, preventing polysulfide solubilization. The main objectives are:
1. To understand and control the ionic conduction mechanisms in these electrolytes.
2. To integrate this solid electrolyte into an innovative Li-S system.
3. To optimize the cathode structure for the solid-state mechanism and evaluate the electrochemical performance on a representative prototype scale.
The PhD candidate will use a wide range of characterization and analysis techniques to carry out this project:
• Formulation and characterization of the organic solid electrolyte: Techniques such as FT-IR and NMR to analyze chemical structures and identify the properties of synthesized materials (DSC, TGA, XRD, etc.).
• Electrochemical characterization: Analyses using electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), and symmetric cell cycling tests to study ionic conduction properties and electrolyte stability.
• Formulation and performance study of the cathode: Formulation of carbon/sulfur composites and sulfur cathodes integrating the solid electrolyte; galvanostatic cycling tests and advanced interface analyses to understand and optimize solid-state sulfur conversion.
The research will progress in three main phases:
1. Development and characterization of the solid electrolyte: Material development, analysis of conduction mechanisms, and optimization of ionic and mechanical properties.
2. Design and optimization of the cathode structure: Improving electrolyte/cathode interfaces for solid-state sulfur conversion.
3. Electrochemical performance evaluation: Experimental validation of prototypes through in-depth tests, including cyclability and power performance.
Sub-THz programmable electromagnetic surfaces based on phase change material switches
Spatiotemporal manipulation of the near- and far-electromagnetic (EM)-field distribution and its interaction with matter in the THz spectrum (0.1-0.6 THz) is of prime importance in the development of future communication, spectroscopy, imaging, holography, and sensing systems. Reconfigurable Intelligent (Meta)Surface (RIS) is a cutting-edge hybrid analogue/digital architecture capable of shaping and controlling the THz waves at the subwavelength scale. To democratize the RIS technology, it will be crucial to reduce its energy consumption by two orders of magnitude. However, the state-of-the-art does not address the integration, scalability, wideband and high-efficiency requirements.
Based on our recent research results, the main objective of this project will be to demonstrate novel silicon-based RIS architectures s at 140 GHz and 300 GHz. The enhancement of the THz RIS performance will derive from a careful choice of the silicon technology and, from novel wideband meta-atom designs (also called unit cell or element) with integrated switches based on PCM (phase change material). The possibility of dynamically controlling the amplitude of the transmission coefficients of the meta-atoms, besides their phase, will be also investigated. Near-field illumination will be introduced to obtain an ultra-low profile. To the best of our knowledge, this constitutes a new approach for the design of high-gain antennas in the sub-THz range.
RF Circuit Design for Zero Energy Communication
Our ambition for 6G communication is to drastically reduce the Energy in IoT. For that purpose we aim at developing an integrated circuit enabling zero Energy communication.
The objective of this PhD is to design this circuit in FD-SOI and operating in the 2.4 GHz. In this PhD, we propose to use a new design technique which is currently revolutionizing the radio-frequency design. We expect that many innovations can be carried out during this PhD by combining those two innovations.
The candidate will integrate a large design team and he will participate in collaborative project at european level. As a first step, he will analyze the system constraints to choose the best architecture and derive the specifications. Then, he will formalize mathematically the performances of the backscattering technique in order to setup a design methodology. Then he will be working full time on circuit design, sending to fabrication two circuits in 22 um technology. He will be also involve in the test of the circuit as well as in the preparation of a demonstrator of the backscattering techniques. We expect to publish several papers in high level conferences.
Learning world models for advanced autonomous agent
World models are internal representations of the external environment that an agent can use to interact with the real world. They are essential for understanding the physics that govern real-world dynamics, making predictions, and planning long-horizon actions. World models can be used to simulate real-world interactions and enhance the interpretability and explainability of an agent's behavior within this environment, making them key components for advanced autonomous agent models.
Nevertheless, building an accurate world model remains challenging. The goal of this PhD is to develop methodology to learn world models and study their use in the context of autonomous driving, particularly for motion forecasting and developing autonomous agents for navigation.
Development of a predictive power model for a photovoltaic device under spatial constraints
CEA is developing new cell and module architectures and simulation tools to assess the electrical performance of photovoltaic (PV) systems in their operating environment. One of these models, called CTMod (Cell To Module), takes into account not only the different materials making up the module, but also the different cell architectures. For space applications, the community wants to use terrestrial silicon-based technologies that can be integrated on flexible PVAs (Photovoltaic Assembly). The space environment imposes severe constraints. A relevant evaluation of performance at the start and end of a mission is therefore essential for their dimensioning.
The aim of this thesis is to correlate physical models of radiation-matter degradation in space with electrical models of photovoltaic cells. Performance degradations linked to the various electron, proton and ultraviolet (UV) irradiations of the space environment will be evaluated and validated experimentally. Linked to the CTMod Model, this new approach, never seen in the literature, will able to get a more accurate understanding of interactions between radiations and PVAs. These degradations result from non-ionizing energy deposition phenomena, quantified by the defect dose per displacement, and ionizing ones quantified by the total ionizing dose for protons and electrons. In the case of UV, the excitation of electrons in matter generates chain breaks in organic materials and colored centers in inorganic materials. Initially, the solar cell used in the model will be a Silicon cell, but the model can be extended to include other types of solar cell under development, such as perovskite-based cells.
Multiphe hydrogen injection at anode side of PEMFC
The alternating feeding architecture (known as Ping-Pong) was developed by the CEA. This architecture emerged in 2013 and has been implemented in several fuel cell systems. Following the latest tests on this architecture, questions remained unanswered. First, it is a question of understanding how species (hydrogen, nitrogen, liquid and gaseous water) move in cells operating with alternating feeding. Control laws influences these movements, it will be necessary to identify the levers to make the most out of it and then to propose methods to promote the evacuation of water and nitrogen while avoiding the evacuation of hydrogen.
The thesis work will aim to optimize the anode architecture with alternating feeding and to bring this architecture to maturity. The key points are the search for an optimum control of this architecture, the achievement of a hydrogen rejection rate of less than 1%. Finally, this optimization will also have to maximize the durability of the stack.
The doctoral student will have to model the movements of species at different time scales (10ms to 10 minutes), understand the mechanisms, adapt the control laws and validate the new control laws on a test bench.
This work will identify solutions to efficiently evacuate liquid water and nitrogen and minimize H2 rejection and then obtain superior performance compared to conventional architectures.
Mesure de la réponse intra-pixel de détecteur infrarouge à base de HgCdTe avec des rayons X pour l’astrophysique
In the field of infrared astrophysics, the most commonly used photon sensors are detector arrays based on the HgCdTe absorbing material. The manufacturing of such detectors is a globally recognized expertise of CEA/Leti in Grenoble. As for the Astrophysics Department (DAp) of CEA/IRFU, it holds renowned expertise in the characterization of this type of detector. A key characteristic is the pixel spatial response (PSR), which describes the response of an individual pixel in the array to the point-like generation of carriers within the absorbing material at various locations inside the pixel. Today, this detector characteristic has become a critical parameter for instrument performance. It is particularly crucial in applications such as measuring galaxy distortion or conducting high-precision astrometry. Various methods exist to measure this quantity, including the projection of point light sources and interferometric techniques. These methods, however, are complex to implement, especially at the cryogenic operating temperatures of the detectors.
At the DAp, we propose a new method based on the use of X-ray photons to measure the PSR of infrared detectors. By interacting with the HgCdTe material, the X-ray photon generates carriers locally. These carriers then diffuse before being collected. The goal is to derive the PSR by analyzing the resulting images. We suggest a two-pronged approach that integrates both experimental methods and simulations. Data analysis methods will also be developed. Thus, the ultimate objective of this thesis is to develop a new, robust, elegant, and fast method for measuring the intra-pixel response of infrared detectors for space instrumentation. The student will be based at the DAp. This work also involves collaboration with CEA/Leti, combining the instrumental expertise of the DAp with the technological knowledge of CEA/Leti.
Development and characterization of a reliable 13.5 nm EUV OAM carrying photon beamline
The Extreme UltraViolet (EUV) photon energy range (10-100 nm) is crucial for many applications spanning from fundamental physics (attophysics, femto-magnetism) to applied domains such as lithography and nanometer scale microscopy. However, there are no natural source of light in this energy domain on Earth because photons are strongly absorbed by matter, requiring thus vacuum environment. People instead have to rely on expensive large-scale sources such as synchrotrons, free electron lasers or plasmas from large lasers. High order laser harmonic generation (HHG), discovered 30 years ago and recognized by the Nobel Prize in Physics in 2023, is a promising alternative as a laboratory scale EUV source. Based on a strongly nonlinear interaction between an ultrashort intense laser and an atomic gas, it results in the emission of EUV pulses with femto to attosecond durations, very high coherence properties and relatively large fluxes. Despite intensive research that have provided a clear understanding of the phenomenon, it has up to know been mostly limited to laboratories. Breaching the gap towards applied industry requires increasing the reliability of the beamlines, subjects to large fluctuations due to the strong nonlinearity of the mechanism, and developing tools to measure and control their properties.
CEA/LIDYL and Imagine Optic have recently joined their expertise in a join laboratory to develop a stable EUV beamline dedicated to metrology and EUV sensors. The NanoLite laboratory, hosted at CEA/LIDYL, is based on a high repetition rate compact HHG beamline providing EUV photons around 40eV. Several EUV wavefront sensors have been successfully calibrated in the past few years. However, new needs have emerged recently, resulting in the need to upgrade the beamline.
The first objective of the PhD will be to install a new HHG geometry to the beamline to enhance its overall stability and efficiency and to increase the photon energy to 92eV, a golden target for lithography. He will then implement the generation of a EUV beam carrying orbital angular momentum and will upgrade Imagine Optic’s detector to characterize its OAM content. Finally, assisted by Imagine Optic engineers, he will develop a new functionality to their wavefront sensors in order to enable large beam characterization.