Wetting dynamics at the nanoscale
Wetting dynamics describes the processes involved when a liquid spreads on a solid surface. It's an ubiquitous phenomenon in nature, for example when dew beads up on a leaf, as well as in many processes of industrial interest, from the spreading of paint on a wall to the development of high-performance coating processes in nanotechnology. Today, wetting dynamics is relatively well understood in the case of perfectly smooth, homogeneous model solid surfaces, but not in the case of real surfaces featuring roughness and/or chemical heterogeneity, for which fine modeling of the mechanisms remains a major challenge. The main goal of this thesis is to understand how nanometric roughness influences wetting dynamics.
This project is based on an interdisciplinary approach combining physics and surface chemistry. The PhD student will conduct systematic model experiments, combined with multi-scale visualization and characterization tools (optical microscopy, AFM, X-ray and neutron reflectivity, etc.).
Thanks to the complementary nature of the experimental approaches, this thesis will provide a better understanding of the fundamental mechanisms of energy dissipation at the contact line, from the nanometric to the millimetric scale.
Experimental study of boundary layers in turbulent convection by diffusive waves spectroscopy
Turbulent convection is one of the main drivers of geophysical and astrophysical flows, and is therefore a key element in climate modeling. It is also involved in many industrial flows. Transport efficiency is often limited by boundary layers whose nature and transitions as a function of control parameters are poorly understood.
The aim of this thesis will be to set up a convection experiment to probe the dissipation rate in boundary layers in the turbulent regime, using an innovative technique developed in the team: multi-scattered wave spectroscopy.
Microemulsion model: Towards the prediction of liquid-liquid extraction processes
This multi-scale modeling thesis aims to develop innovative theoretical approaches and numerical tools to revolutionize strategic metal extraction processes, such as liquid-liquid extraction, whose underlying mechanisms remain poorly understood. To address these challenges, solvent phases will be represented as microemulsions through a synergy of mesoscopic and molecular modeling approaches.
The mesoscopic approach will involve the development of a code based on microemulsion theory using a random wavelet basis. This code will enable the characterization of the structural and thermodynamic properties of the solutions. The molecular approach will rely on classical molecular dynamics simulations to evaluate the curvature properties of the extractants, which are essential for bridging the two scales.
The new high-performance computational code may integrate artificial intelligence techniques to accelerate the minimization of the system’s free energy while accounting for all chemical species present with a minimal number of parameters. This will pave the way for new research directions, such as predicting speciation and calculating thermodynamic instabilities in ternary phase diagrams, thereby identifying unexplored experimental conditions.
This PhD thesis, conducted at the Mesoscopic Modeling and Theoretical Chemistry Laboratory at the Marcoule Institute for Separation Chemistry, will have applications in the recycling domain and extend to the broader field of nanoscience, thereby expanding the impact of this work.
The PhD candidate, with an academic background in physical chemistry, theoretical chemistry, or physics, and a strong interest in programming, will be encouraged to disseminate his/her scientific results through publications and presentations at national and international conferences. Upon completion of the thesis, the candidate will have acquired a wide range of skills in modeling and physical chemistry, opening numerous professional opportunities in both academic research and industrial R&D.
Experimental and theoretical study of rheology and migration of particle suspensions in bitumen
Waste management is an important area of research for nuclear energy which is an essential building block for the development of low-carbon energies. This thesis focuses on understanding the mechanical and thermal behavior of a particular type of waste: bituminous matrices. This understanding is essential to contribute to its nuclear safety. In this context, we propose an experimental study of the mechanical behavior of a bituminous mix composed of salt grains of various sizes and chemical natures, as well as gas bubbles. More specifically, the aim is to characterize the impact of these elements on the rheology of the material, and to study the effects of salt sedimentation or bubble migration. To this end, bituminous mixes of various types will be synthesized. They will then be characterized in terms of rheology and imaging (2D by Optical Microscopy (OM) or Scanning Electron Microscopy (SEM), and 3D by X-ray tomography) over time. Rheological and sedimentation models will be developed on the basis of experimental results and implemented in existing codes developed at CEA.
The applicant will have access to a high-level analytical platform and a dedicated laboratory infrastructure that will enable him/her to acquire expertise in the field of materials analysis and properties that can be leveraged for his/her professional project.
Rheology of concentrated mineral-filled suspensions
As a research organization in the nuclear field and alternative energies, the CEA participates in fundamental studies involving dense suspensions. Inorganic particles (glass, zeolite, sludge, salts, or cement/sand) suspended in fluids, sometimes with very high viscosity like bitumen, are part of the systems under study for various applications. These include optimizing the filling of glass packages (Dem N' Melt process) or cement packages, where flow properties need to be optimized to ensure homogeneity of waste drums. Besides to addressing the recovery (historical sludges), treatment, and conditioning of waste in glass or bituminous matrices, concentrated suspensions of glass grains are being studied for high-temperature electrolysis production of dihydrogen.
In this optic, the research will initially focus on model concentrated suspensions, characterizing their flow properties under shear and compression. This latter type of mechanical test can trigger the appearance of frictional regimes, liquid/solid phase separation, and various non-linear responses that will need to be modeled. After this first stage, the topology, particle size distribution, and polydispersity of the solid particles will be varied to be as close as possible to the suspensions encountered in industry.