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Home   /   Thesis   /   Development of high-halogen argyrodites for all-solid all-sulfide systems

Development of high-halogen argyrodites for all-solid all-sulfide systems

Condensed matter physics, chemistry & nanosciences Electrochemical energy storage incl. batteries for energy transition Physical chemistry and electrochemistry Technological challenges


All-solid-state batteries have been enjoying renewed interest in recent years, as this technology offers the prospect of higher energy densities due to the use of lithium as a negative electrode, as well as increased battery safety compared with Li-ion technology. The use of sulfides as positive electrode materials coupled with argyrodite as solid electrolyte are interesting systems to develop. The argyrodites achieve ionic conductivities close to those of liquid electrolytes. Moreover, the electrochemical stability window of sulfides is close to that of argyrodite, making all-sulfide technology a promising one for the development of all-solid batteries.
In order to improve the conduction properties of argyrodites, recent studies have shown that ionic conductivity is highly dependent on their local structure. Solid-state NMR thus appears to be a promising technique for probing the local environments of the nuclei mentioned, and in particular for quantifying the variety of different local environments favoring an increase in ionic conductivity. Some compositions enriched in halides appear to promote ionic conduction, and the synthesis of corresponding materials and their structure will be studied.
The thesis will focus on two main areas: the study of all-sulfide batteries and the fine characterization of argyrodite with controlled local structures. Halogen-rich argyrodites will be developed and studied to determine the influence of different local environments on conduction properties.


Département de l’Electricité et de l’Hydrogène pour les Transports (LITEN)
Service Technologies Batterie
Laboratoire Matériaux
Université Grenoble Alpes
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