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Home   /   Thesis   /   Predictive modeling of the alteration of nuclear waste containment glass.

Predictive modeling of the alteration of nuclear waste containment glass.

Earth and environmental sciences Engineering sciences Environment and pollution Mathematics - Numerical analysis - Simulation


In France, vitrified waste from nuclear fuel processing is to be disposed deep underground in clay geological strata. In this confined, low-porosity environment, the chemical interaction between the glass, the corrosion products of the metal containers and the site clay should control the weathering of the glass once the medium is again saturated with water. Predicting the long-term weathering of vitrified packages requires a thorough understanding of the many interrelated reaction mechanisms involved. In practice, these mechanisms are classified according to their importance on weathering kinetics, and then integrated within models adapted to the relevant time and space scales.
This thesis focuses on the geochemical modeling of glass weathering, which is carried out using a reactive transport code (CHESS/HYTEC), a thermodynamic database and a kinetic law for glasses (GRAAL2 model, derived from the GRAAL model (Frugier et al. 2018)). This model takes into account the role of the composition of the glass weathering layer on its protective character, enabling GRAAL2 to simulate variations in weathering rate as a function of glass composition and environmental conditions.
We are looking for a student with a master's degree related to modeling or geochemistry, strong Python programming skills, and an interest in understanding processes through models. At the end of these three years, the student will have gained a strong understanding of geochemical modeling (using the CHESS code), mass transfer modeling (using the Hytec code), glass alteration modeling (with the GRAAL2 model), as well as skills in numerical programming in Python. The student will also develop a deep understanding of concepts related to deviation, error, and uncertainty. He will become familiar with issues related to the transfer of pollutants in the environment and nuclear waste management. The knowledge and skills acquired are important in various fields related to material sustainability, the environment, and modeling, including the rigorous methodologies that underlie these approaches.


Département de recherche sur les Procédés et Matériaux pour les Environnements complexes
Service d’Etudes des Matériaux et de l’Etanchéité
Laboratoire d’Etude des Matériaux en environnement Complexe
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