About us
Espace utilisateur
INSTN offers more than 40 diplomas from operator level to post-graduate degree level. 30% of our students are international students.
Professionnal development
Professionnal development
Find a training course
INSTN delivers off-the-self or tailor-made training courses to support the operational excellence of your talents.
Human capital solutions
At INSTN, we are committed to providing our partners with the best human capital solutions to develop and deliver safe & sustainable projects.
Home   /   Thesis   /   Solid-state batteries based on composite polymer-ceramic electrolytes : multi-scale characterization and understanding of phenomena at interfaces

Solid-state batteries based on composite polymer-ceramic electrolytes : multi-scale characterization and understanding of phenomena at interfaces


Lithium-ion batteries, widely present in our daily lives, have revolutionized portable applications and are now used in electric vehicles. However, the development of new generations of batteries for future applications in transport and storing electricity from renewable sources is vital to mitigating climate change.

Sodium is more abundant on earth than lithium and therefore attractive in particular for large-scale stationary storage applications. Lithium-ion technology is generally considered as the preferred solution for applications requiring high energy density, while sodium-ion technology is particularly attractive for applications requiring power.

However, liquid electrolyte batteries present environmental risks such as leaks and can occasionally experience safety problems. Faced with the requirements concerning the environment and safety, solid-state batteries based on solid electrolytes can provide an effective solution while meeting battery energy storage needs. The barriers to overcome allowing the development of all-solid-state battery technology consist mainly in the research of new chemically stable solid electrolytes with good electrical, electrochemical and mechanical performance. For this goal, this thesis project aims to develop “ceramic / polymer” composite solid electrolytes with high performance and enhanced safety. Characterizations by electrochemical impedance spectroscopy (EIS) will be carried out in order to understand the cation dynamics (by Li+ or Na+) at the macroscopic scale in composite electrolytes, while the local dynamics will be probed using advanced techniques of Solid state NMR (23Na / 7Li relaxation, 2D NMR, in-situ NMR & operando). Other characterization techniques such as X-ray and neutron diffraction, XPS, chronoamperometry, GITT ... will be implemented for a perfect understanding of the structure of electrolytes as well as aging mechanisms at the electrolyte / electrolyte and electrolyte/electrode interfaces of the all-solid battery.

Key words: composite solid electrolyte, all-solid-state battery, interfaces, multiscale characterization, dynamics of Li + and Na + ions, electrochemical performance, solid-state NMR, X-ray / neutron diffraction.


Institut rayonnement et matière de Saclay
Service Nanosciences et Innovation pour les Materiaux, la Biomédecine et l’Energie
Laboratoire d’étude des éléments légers
Top envelopegraduation-hatlicensebookuserusersmap-markercalendar-fullbubblecrossmenuarrow-down