As the national metrology laboratory for ionizing radiation, the Henri Becquerel National Laboratory (LNE-LNHB) of the French Alternative Energies and Atomic Energy Commission (CEA) operates unique facilities dedicated to radionuclide metrology. These include various setups for producing liquid-phase standards, as well as systems for mixing radioactive gases. In previous research projects, a specific installation was developed for the generation of radioactive gas atmospheres [1], with the aim of creating new testing and calibration methods that meet the needs of both research and industry.

One of the major current challenges is to reproduce environmental conditions as realistically as possible in order to better address actual regulatory requirements—particularly regarding volumetric activity and measurement conditions. This general issue applies to all radioactive substances, but is especially critical for volatile radioactive substances. Over the past several years, through numerous projects and collaborations, CEA/LNHB has been exploring new detection methods that outperform traditional liquid scintillation techniques. Among these innovations are new porous inorganic scintillators [1], which enable not only online detection but also online separation (“unmixing”) of pure beta-emitting radionuclides—this technique has been patented [2].

The objective of this PhD project is to develop, implement, and optimize these measurement methods through applications to:

- Pure radioactive gases,
- Multicomponent mixtures of pure beta-emitting radioactive gases—using porous scintillators for unmixing and identification,
- Liquid scintillation counting, more generally, where this unmixing capability has recently been demonstrated at LNHB and is currently being prepared for publication.

The unmixing technique is of particular interest, as it significantly simplifies environmental monitoring by scintillation, especially in the case of ³H and ¹4C mixtures. Currently, such analyses require multiple bubbler samplings, mixing with scintillation cocktail, and triple-label methods—procedures that involve several months of calibration preparation and weeks of experimentation and processing.

This PhD will be closely aligned with a second doctoral project on Compton-TDCR [1] (2025–2028), aimed at determining the response curve of the scintillators.

The scientific challenges of the project are tied to radionuclide metrology and combine experimentation, instrumentation, and data analysis to develop innovative measurement techniques. Key objectives include:

- Developing a method for beta-emitter unmixing in scintillation, based on initial published and patented concepts.
- Assessing the precision of the unmixing method, including associated uncertainties and decision thresholds.
- Validating the unmixing technique using the laboratory’s radioactive gas test bench [1], with various radionuclides such as 3H, 14C, 133Xe, 85Kr, 222Rn,... or via conventional liquid scintillation counting.
- Enhancing the unmixing model, potentially through the use of machine learning or artificial intelligence tools, particularly for complex multicomponent mixtures.