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Thesis
Home   /   Thesis   /   Mechanical degradation of Solid Oxide Cells: impact of operating and failure modes on the performances

Mechanical degradation of Solid Oxide Cells: impact of operating and failure modes on the performances

Condensed matter physics, chemistry & nanosciences Engineering sciences Materials and applications Physical chemistry and electrochemistry

Abstract

Solid oxide cells (SOCs) are electrochemical devices operating at high temperature that can directly convert fuel into electricity (fuel cell mode – SOFC) or electricity into fuel (electrolysis mode – SOEC). In recent years, the interest on SOCs has grown significantly thanks to their wide range of technological applications that could offer innovative solutions for the transition toward a renewable energy market. However, despite of all their advantages, the large-scale industrialization of this technology is still hindered by the durability of SOCs. Indeed, the SOCs remain limited by various degradation phenomena including mechanical damage in the electrodes. For instance, the formation of micro-cracks in the so-called ‘hydrogen’ electrode is a major source of degradation. However, the precise mechanism and the full impact of the micro-cracks on the electrode performances are still unknown. By a multi-physic modelling approach, it is proposed in this thesis (i) to simulate the damage in the microstructure of the electrode and (ii) to calculate its impact on the loss of performances. Once the model validated on dedicated experiments, a sensitivity analysis will be conducted to provide relevant guidelines for the manufacturing of improved robust and performant electrodes.

Laboratory

Département Thermique Conversion et Hydrogène (LITEN)
Service des technologies hydrogène
Laboratoire essais et systèmes
Université Grenoble Alpes
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