In the context of the sustainable and safe use of nuclear energy within a carbon-free energy mix that addresses the climate emergency, managing radioactive waste inventory is a priority concern. The alteration of nuclear glass therefore directly affects the long-term assessment of the safety of geological storage of this waste. Understanding and simulating these processes is therefore a major scientific, industrial, and societal challenge. Existing models, such as GRAAL2 [1] developed at the CEA, capture the passivation mechanisms governing glass alteration, bridging nanometric processes to mesoscopic scale through mesoscopic-scale kinetic laws used in reactive transport codes (RTC).
This PhD aims to develop an autonomous glass module (GM) based on the GRAAL2 model, capable of computing glass alteration kinetics and interfacing with different reactive transport codes (HYTEC, CRUNCH…). The main objectives are: (i) to design and implement a kinetic module, (ii) to develop a coupling interface managing information exchange with RTC, (iii) to define and carry out numerical validation campaigns on reference test cases for both the GM and the coupler, and (iv) to perform sensitivity and uncertainty analyses to identify the key parameters controlling glass behavior in a multi-material context (glass, iron, clay).
The PhD will take place at the Laboratory for Environmental Transfer Modeling (LMTE), within the IRESNE Institute (CEA, Cadarache site, Saint-Paul-lès-Durance). The project will provide the PhD candidate with cross-disciplinary skills in geochemistry, multiphysics coupling, and scientific software development, opening career opportunities in both academic research and nuclear/environmental engineering.

References:
[1] M. Delcroix, P. Frugier, E. Geiger, C. Noiriel, The GRAAL2 glass alteration model: initial qualification on a simple chemical system, Npj Mater Degrad 9 (2025) 38. https://doi.org/10.1038/s41529-025-00589-4.