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Thesis
Home   /   Thesis   /   oxygen ordering in zirconium: mechanisms, kinetics and associated mechanical properties

oxygen ordering in zirconium: mechanisms, kinetics and associated mechanical properties

Engineering sciences Materials and applications

Abstract

The aim of this work is to study the properties of binary zirconium-oxygen (Zr-O) alloys, particularly in the context of nuclear applications. Traditionally, oxygen is considered to be in solid solution in the zirconium matrix, without the formation of ordered compounds such as Zr6O or Zr3O. However, recent studies suggest that at temperatures below 600°C, ordered compounds can form, affecting the solubility limit of oxygen. These compounds, observed after heat treatments, could modify the mechanical properties of Zr-O alloys, particularly at room temperature and up to 350°C. The proposed thesis seeks to understand these mechanisms through X-ray diffraction and electron microscopy experiments, in order to study the arrangement of oxygen, the thermal stability of the compounds and their impact on plastic deformation. The aim is to optimise the use of these alloys in nuclear reactors.

Laboratory

Département de Recherche sur les Matériaux et la Physico-chimie pour les énergies bas carbone
Service de Recherche en Matériaux et procédés Avancés
Laboratoire d’Analyse Microstructurale des Matériaux
Paris Sciences et Lettres
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