



Silicon-based photovoltaic cells, particularly silicon heterojunction (SHJ) cells using hydrogenated amorphous silicon (a-Si:H), achieve efficiencies exceeding 25%. However, these architectures exhibit intrinsic metastability, such as Staebler-Wronski degradation, which can lead to efficiency losses during storage between fabrication and module assembly. In the context of globalized supply chains, these instabilities represent an economic and technical risk that is not yet well quantified. This thesis aims to address the following questions: what is the quantitative impact of instability on the efficiency of high-efficiency cells during prolonged storage? What are the physical mechanisms responsible for this degradation? What technological strategies can reduce or eliminate this instability? What are the industrial implications for module logistics? To achieve this, a rigorous experimental protocol will be implemented to monitor the electrical performance of cells over several months under varying storage conditions (atmosphere, temperature, humidity). Test structures and advanced characterizations (FTIR, Raman, Silvaco TCAD) will be used to understand the underlying physical phenomena. Process optimization, introduction of new materials, and improved packaging will be explored to stabilize the cells. Practical recommendations for the industry, regarding maximum storage durations and optimal storage conditions, will also be established. The goal is to develop technological and logistical solutions to minimize efficiency losses in SHJ cells, optimize supply chains, and reduce associated economic risks.

